Bis[(2-dimethylamino)phenyl]amine nickel(II) chloride

• Catalog No.: 728551
• CAS Number: 1033772-47-2
• M. F.: C16H20ClN3Ni
• M. W.: 348.4965
• Purity: ≥97% (AT)

SYNONYMS

• Title: 双[(2-二甲氨基)苯基]胺氯化镍(II)
• IUPAC name: 1-N-(chloronickelio)-1-N-[2-(dimethylamino)phenyl]-2-N,2-N-dimethylbenzene-1,2-diamine
• IUPAC Traditional name: 1-N-(chloronickelio)-1-N-[2-(dimethylamino)phenyl]-2-N,2-N-dimethylbenzene-1,2-diamine
• Synonyms: Nickamine; Chloro[N2-[2-(dimethylamino-κN)phenyl]-N1,N1-dimethyl-1,2-benzenediaminato-κN1,κN2]-nickel; 氯[N2-[2-(二甲氨基-κN)苯基]-N1,N1-二甲基-1,2-苯二胺-κN1,κN2]-镍

DATABASE IDS

• MDL Number: MFCD17015253
• CAS Number: 1033772-47-2

PROPERTIES

• Empirical Formula (Hill Notation): C16H20ClN3Ni
• Purity: ≥97% (AT)
• German water hazard class: 3

DETAILS

Description (English)

Packaging
100, 500 mg in glass bottle
Application
Catalyst for:
• Alkyl-alkyl Kumada coupling of secondary alkyl halides1
• Direct alkylation of heterocyclic C-H bonds2
• Sonogashira coupling of nonactivated alkyl halides3
• Kumada-Corriu-Tamao coupling of nonactivated alkyl halides with aryl and heteroaryl nucleophiles4Reactant of pincer NN2 ligand leading to selective carbon-carbon bond formation5

Description (简体中文)

包装
100, 500 mg in glass bottle
Application
Catalyst for:
• Alkyl-alkyl Kumada coupling of secondary alkyl halides1
• Direct alkylation of heterocyclic C-H bonds2
• Sonogashira coupling of nonactivated alkyl halides3
• Kumada-Corriu-Tamao coupling of nonactivated alkyl halides with aryl and heteroaryl nucleophiles4Reactant of pincer NN2 ligand leading to selective carbon-carbon bond formation5