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Hydrogen[4-[bis(2,4,6-trimethylphenyl)phosphino]-2,3,5,6-tetrafluorophenyl]hydrobis(2,3,4,5,6-pentafluorophenyl)borate_Molecular_structure_CAS_918824-12-1)
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Hydrogen[4-[bis(2,4,6-trimethylphenyl)phosphino]-2,3,5,6-tetrafluorophenyl]hydrobis(2,3,4,5,6-pentafluorophenyl)borate

Catalog No. 703095 Name Sigma Aldrich
CAS Number 918824-12-1 Website http://www.sigmaaldrich.com
M. F. C36H22BF14P Telephone 1-800-521-8956
M. W. 762.3222858 Fax
Purity 95% Email
Storage Chembase ID: 143266

SYNONYMS

Title
氢[4-[双(2,4,6-三甲苯)膦]-2,3,5,6-四氟苯]氢双(2,3,4,5,6-五氟苯)硼酸盐
IUPAC name
{4-[bis(2,4,6-trimethylphenyl)phosphaniumyl]-2,3,5,6-tetrafluorophenyl}bis(pentafluorophenyl)boranuide
IUPAC Traditional name
{4-[bis(2,4,6-trimethylphenyl)phosphaniumyl]-2,3,5,6-tetrafluorophenyl}bis(pentafluorophenyl)boranuide
Synonyms
Frustrated phosphonium borate 2
氢[4-[双均三甲苯基膦]-2,3,5,6-四氟苯]氢双(2,3,4,5,6-五氟苯)硼酸盐
Hydrogen[4-[dimesitylphosphino]-2,3,5,6-tetrafluorophenyl]hydrobis(2,3,4,5,6-pentafluorophenyl)borate

DATABASE IDS

CAS Number 918824-12-1
MDL Number MFCD16621393

PROPERTIES

MSDS Link Download
GHS Precautionary statements P261-P305 + P351 + P338
Risk Statements 36/37/38
Safety Statements 26
Storage Temperature 2-8°C
German water hazard class 3
GHS Pictograms GHS07
GHS Signal Word Warning
GHS Hazard statements H315-H319-H335
European Hazard Symbols Irritant Irritant (Xi)
Linear Formula H+[(((CH3)3C6H2)2PC6F4)B(H) (C6F5)2]-
Purity 95%
Melting Point 211-216 °C

DETAILS

Description (English)
Application
Frustrated phosphonium borate for metal-free catalytic hydrogenation of imines. Activates dihydrogen under mild conditions.1,3
Catalyst for metal-free hydrogenation1Reactant for:
• Formation of phosphine-boranes and cationic phosphonium-boranes2
• Metal-free hydrogen activation3
Packaging
250 mg in glass bottle
Description (简体中文)
Application
用于亚胺的无金属催化氢化反应的不稳定膦硼酸盐。在温和条件下激活二氢。1,3
Catalyst for metal-free hydrogenation1Reactant for:
• Formation of phosphine-boranes and cationic phosphonium-boranes2
• Metal-free hydrogen activation3
包装
250 mg in glass bottle

REFERENCES