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Bis(3,5-dimethyl-4-methoxyphenyl)chlorophosphine_Molecular_structure_CAS_136802-85-2)
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Bis(3,5-dimethyl-4-methoxyphenyl)chlorophosphine

Catalog No. 710385 Name Sigma Aldrich
CAS Number 136802-85-2 Website http://www.sigmaaldrich.com
M. F. C18H22ClO2P Telephone 1-800-521-8956
M. W. 336.792841 Fax
Purity 95% Email
Storage Chembase ID: 142469

SYNONYMS

Title
氯二(3,5-二甲基-4-甲氧苯基)膦
IUPAC name
chlorobis(4-methoxy-3,5-dimethylphenyl)phosphane
IUPAC Traditional name
chlorobis(4-methoxy-3,5-dimethylphenyl)phosphane

DATABASE IDS

MDL Number MFCD01630810
CAS Number 136802-85-2

PROPERTIES

Empirical Formula (Hill Notation) C18H22ClO2P
Purity 95%
Density 1.141 g/cm3 at 25 °C
Flash Point >110 °C
Flash Point >230 °F
Refractive Index n20/D 1.597
GHS Pictograms GHS05
GHS Signal Word Danger
GHS Hazard statements H314
European Hazard Symbols Corrosive Corrosive (C)
MSDS Link Download
GHS Precautionary statements P280-P305 + P351 + P338-P310
RID/ADR UN 1760 8/PG 3
Risk Statements 34
Safety Statements 26-36/37/39-43-45
Hazard Class 8
UN Number 1760
Packing Group 3
German water hazard class 3

DETAILS

Description (English)
Packaging
1 g in glass bottle
Application
Reactant for:
• Asymmetric organocatalytic electrophilic phosphination1
• Asymmetric hydroformulation using Taddol-based chiral phosphine-phosphite ligands2
• Synthesis of ferrocene-based chiral diphosphines3
• Alcoholysis of phosphane-boranes4
• Asymmetric hydrogenations of bifep-type biferrocenes5
Description (简体中文)
包装
1 g in glass bottle
Application
Reactant for:
• Asymmetric organocatalytic electrophilic phosphination1
• Asymmetric hydroformulation using Taddol-based chiral phosphine-phosphite ligands2
• Synthesis of ferrocene-based chiral diphosphines3
• Alcoholysis of phosphane-boranes4
• Asymmetric hydrogenations of bifep-type biferrocenes5

REFERENCES