Tris[N,N-Bis(trimethylsilyl)amide]gadolinium(III)

• Catalog No.: 547824
• CAS Number: 35789-03-8
• M. F.: C18H54GdN3Si6
• M. W.: 638.40446
• Purity: 98%

SYNONYMS

• Title: 三[N,N-双(三甲基甲硅烷基)酰胺]钆(III)
• IUPAC name: 2,2,6,6-tetramethyl-N,N,3,5-tetrakis(trimethylsilyl)-3,5-diaza-2,6-disila-4-gadolinaheptan-4-amine
• IUPAC Traditional name: 2,2,6,6-tetramethyl-N,N,3,5-tetrakis(trimethylsilyl)-3,5-diaza-2,6-disila-4-gadolinaheptan-4-amine

DATABASE IDS

• PubChem SID: 24878983
• CAS Number: 35789-03-8
• MDL Number: MFCD03427091

PROPERTIES

• Linear Formula: Gd(N(Si(CH3)3)2)3
• Purity: 98%
• Apperance: solid
• Flash Point: 2 °C
• Flash Point: 35.6 °F
• Melting Point: 67-90 °C(lit.)
• GHS Signal Word: Danger
• GHS Hazard statements: H228-H261-H314
• European Hazard Symbols: Flammable (F)
• European Hazard Symbols: Corrosive (C)
• Personal Protective Equipment: Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
• GHS Precautionary statements: P210-P231 + P232-P280-P305 + P351 + P338-P310-P422
• RID/ADR: UN 3396 4.3/PG 2
• Risk Statements: 11-14/15-34
• Safety Statements: 7/8-16-26-36/37/39-43-45
• Supplemental Hazard Statements: Reacts violently with water.
• Hazard Class: 4.3
• UN Number: 3396
• Packing Group: 2
• German water hazard class: 3

DETAILS

Description (English)

Application
In many asymmetric catalysis applications, glove box and Schlenk techniques should be employed to prevent exposure of the rare earth catalyst to air and moisture, which can be detrimental to the reaction outcome. Solutions of the catalyst should be made using anhydrous solvents and used shortly after preparation.
General description
Atomic number of base material: 64 Gadolinium
Packaging
1 g in glass bottle

Description (简体中文)

Application
在很多不对称催化应用中，应当使用手套箱和 Schlenk 技术防止此稀土催化剂与空气和水分接触，因为这两个因素将对反应结果产生不利影响。用无水溶剂配制该催化剂溶液并立即使用。
General description
Atomic number of base material: 64 Gadolinium
包装
1 g in glass bottle