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Hydrogen [4-di-tert-butylphosphino-2,3,5,6-tetrafluorophenyl]hydrobis(2,3,4,5,6-pentafluorophenyl)borate_Molecular_structure_CAS_952208-49-0)
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Hydrogen [4-di-tert-butylphosphino-2,3,5,6-tetrafluorophenyl]hydrobis(2,3,4,5,6-pentafluorophenyl)borate

Catalog No. 703087 Name Sigma Aldrich
CAS Number 952208-49-0 Website http://www.sigmaaldrich.com
M. F. C26H18BF14P- Telephone 1-800-521-8956
M. W. 638.1835258 Fax
Purity 97% Email
Storage Chembase ID: 143152

SYNONYMS

Title
氢[4-二-叔丁基膦-2,3,5,6-四氟苯]氢双(2,3,4,5,6-五氟苯)硼酸盐
IUPAC name
hydrogen [4-(di-tert-butylphosphanyl)-2,3,5,6-tetrafluorophenyl]bis(pentafluorophenyl)boranuide
IUPAC Traditional name
hydrogen [4-(di-tert-butylphosphanyl)-2,3,5,6-tetrafluorophenyl]bis(pentafluorophenyl)boranuide
Synonyms
Frustrated phosphonium borate 1

DATABASE IDS

CAS Number 952208-49-0

PROPERTIES

Linear Formula H+ [(((CH3)3C)2PC6F4)B(H)(C6F5)2]-
Purity 97%
Melting Point 222-227 °C
GHS Pictograms GHS07
GHS Signal Word Warning
GHS Hazard statements H315-H319-H335
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
GHS Precautionary statements P261-P305 + P351 + P338
Risk Statements 36/37/38
Safety Statements 26-36/37
Storage Temperature 2-8°C
German water hazard class 3

DETAILS

Description (English)
General description
Frustrated phosphonium borate for metal-free catalytic hydrogenation of imines. Activates dihydrogen under mild conditions.1,4
Packaging
1 g in glass bottle
250 mg in glass bottle
Application
Catalyst for metal-free catalytic hydrogenation1Reactant for formation of:
• Frustrated Lewis reactants2
• Phosphine-boranes and cationic phosphonium-boranes3
Description (简体中文)
General description
用于亚胺的无金属催化氢化反应的不稳定膦硼酸盐。在温和条件下激活二氢。1,4
包装
1 g in glass bottle
250 mg in glass bottle
Application
Catalyst for metal-free catalytic hydrogenation1Reactant for formation of:
• Frustrated Lewis reactants2
• Phosphine-boranes and cationic phosphonium-boranes3

REFERENCES