(2S,2′S-(-)-[N,N′-Bis(2-pyridylmethyl)]-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate

• Catalog No.: 730459
• CAS Number: 959395-10-9
• M. F.: C24H32F12FeN6Sb2
• M. W.: 931.8969184

SYNONYMS

• Title: (2S,2′S-(-)-[N,N′-双(2-吡啶基甲基)]-2,2′-二吡咯烷双(乙腈)六氟锑酸铁(II)
• IUPAC name: λ^2-iron(2+) ion 2-{[(2R)-2-[(2R)-1-(pyridin-2-ylmethyl)pyrrolidin-2-yl]pyrrolidin-1-yl]methyl}pyridine bis(acetonitrile) bis(hexafluorostibanuide)
• IUPAC Traditional name: λ^2-iron(2+) ion 2-{[(2R)-2-[(2R)-1-(pyridin-2-ylmethyl)pyrrolidin-2-yl]pyrrolidin-1-yl]methyl}pyridine bis(acetonitrile) bis(hexafluorostibanuide)
• Synonyms: (S,S-(2-({(S)-2-[(S)-1-(吡啶-2-基甲基)吡咯烷-2-基]吡咯烷-1-基}甲基)吡啶)(双-乙腈)六氟锑酸铁(II); White Catalyst; Fe(S,S-PDP); [Fe(S,S-PDP)(CH3CN)2](SbF6)2; Iron(II) (S,S-(2-({(S)-2-[(S)-1-(pyridin-2-ylmethyl)pyrrolidin-2-yl]pyrrolidin-1-yl}methyl)pyridine)(bis-acetonitrile) hexafluoroantimonate; White-Chen 催化剂

DATABASE IDS

• MDL Number: MFCD16038114
• CAS Number: 959395-10-9

PROPERTIES

• Empirical Formula (Hill Notation): C24H32F12FeN6Sb2
• Melting Point: >300 °C
• Optical Rotation: [α]20/D -30.0 to -20.0°, c = 0.2 in acetonitrile
• GHS Signal Word: Warning
• GHS Hazard statements: H315-H319-H335
• European Hazard Symbols: Irritant (Xi)
• GHS Precautionary statements: P261-P305 + P351 + P338
• Risk Statements: 36/37/38
• Safety Statements: 26

DETAILS

Description (English)

Packaging
100, 500 mg in glass bottle
Application
Catalyst for:
• Oxidative radical reactions1
• Selective oxidation of alkyl carbon-hydrogen bonds2
• Methylene group oxidation3

Description (简体中文)

包装
100, 500 mg in glass bottle
Application
Catalyst for:
• Oxidative radical reactions1
• Selective oxidation of alkyl carbon-hydrogen bonds2
• Methylene group oxidation3