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Dichlorobis(1-neomenthylindenyl)-zirconium_Molecular_structure_CAS_148347-88-0)
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Dichlorobis(1-neomenthylindenyl)-zirconium

Catalog No. 719072 Name Sigma Aldrich
CAS Number 148347-88-0 Website http://www.sigmaaldrich.com
M. F. C38H50Cl2Zr Telephone 1-800-521-8956
M. W. 668.9336 Fax
Purity 95% Email
Storage Chembase ID: 143082

SYNONYMS

Title
二氯双(1-新甲基茚基)-锆
IUPAC name
bis(3-[(1S,2S,5R)-5-methyl-2-(propan-2-yl)cyclohexyl]-1H-inden-1-ide); dichlorozirconiumbis(ylium)
IUPAC Traditional name
bis(3-[(1S,2S,5R)-2-isopropyl-5-methylcyclohexyl]-1H-inden-1-ide); dichlorozirconiumbis(ylium)
Synonyms
Dichlorobis[(1,2,3,3a,7a-η)-1-[(1S,2S,5R)-5-methyl-2-(1-methylethyl)cyclohexyl]-1H-inden-1-yl]-zirconium
ZACA 催化剂
ZACA catalyst

DATABASE IDS

MDL Number MFCD06798305
CAS Number 148347-88-0

PROPERTIES

Empirical Formula (Hill Notation) C38H50Cl2Zr
Purity 95%
Melting Point >195 °C (dec.)
MSDS Link Download
German water hazard class nwg

DETAILS

Description (English)
Application
Prof. Ei-ich Negishi′s group has reported the Zirconium-Catalyzed Asymmetric Carboalumination of Alkenes (ZACA) reaction. The ZACA catalyst is a prototypical catalyst for asymmetric carbon-carbon bond formation, used for the efficient and selective synthesis of chiral organic compounds and natural products.5,6,7,8,9
Catalyst for:
• Carboalumination of alkenes1
• Asymmetric carboalumination2
• Intramolecular olefin coupling3
• Polymerization of propylene4
Packaging
100 mg in glass bottle
Description (简体中文)
Application
Prof. Ei-ich Negishi′s group has reported the Zirconium-Catalyzed Asymmetric Carboalumination of Alkenes (ZACA) reaction. The ZACA catalyst is a prototypical catalyst for asymmetric carbon-carbon bond formation, used for the efficient and selective synthesis of chiral organic compounds and natural products.5,6,7,8,9
Catalyst for:
• Carboalumination of alkenes1
• Asymmetric carboalumination2
• Intramolecular olefin coupling3
• Polymerization of propylene4
包装
100 mg in glass bottle

REFERENCES