(1S,2S)-N,N′-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II)

• Catalog No.: 708844
• CAS Number: 259259-80-8
• M. F.: C32H38CoN2O4
• M. W.: 573.58832

SYNONYMS

• Title: (1S,2S)-N,N′-双(2-乙酰-3-氧代-2-亚丁烯基)-1,2-二均三甲苯基乙二胺合钴(II)
• IUPAC name: 1-[(8S,9S)-12-acetyl-4,13-dimethyl-8,9-bis(2,4,6-trimethylphenyl)-1,3-dioxa-7,10-diaza-2-cobaltacyclotrideca-4,6,10,12-tetraen-5-yl]ethan-1-one
• IUPAC Traditional name: 1-[(8S,9S)-12-acetyl-4,13-dimethyl-8,9-bis(2,4,6-trimethylphenyl)-1,3-dioxa-7,10-diaza-2-cobaltacyclotrideca-4,6,10,12-tetraen-5-yl]ethanone
• Synonyms: (S,S)-AMAC

DATABASE IDS

• MDL Number: MFCD06797062
• CAS Number: 259259-80-8

PROPERTIES

• Empirical Formula (Hill Notation): C32H38CoN2O4
• Melting Point: 242-246 °C
• Optical Rotation: [α]/D -309°, c = 0.1 in chloroform
• Personal Protective Equipment: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• German water hazard class: 3

DETAILS

Description (English)

Packaging
100, 500 mg in glass bottle
Application
Catalyst for:
• Stereoselective preparation of benzylic alcohols via oxidative kinetic resolution of secondary benzylic alcohols with oxygen in presence of alkene1
• Enantioselective borohydride reduction2
• Preparation of β-nitro alcohols from aldehydes and nitroalkanes by stereoselective Henry reaction in presence of amine bases3
• Preparation of optically pure diarylpropanediols via reduction of the corresponding diketones4

Description (简体中文)

包装
100, 500 mg in glass bottle
Application
Catalyst for:
• Stereoselective preparation of benzylic alcohols via oxidative kinetic resolution of secondary benzylic alcohols with oxygen in presence of alkene1
• Enantioselective borohydride reduction2
• Preparation of β-nitro alcohols from aldehydes and nitroalkanes by stereoselective Henry reaction in presence of amine bases3
• Preparation of optically pure diarylpropanediols via reduction of the corresponding diketones4