(1R,2R)-N,N′-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II)

• Catalog No.: 708550
• CAS Number: 361346-80-7
• M. F.: C32H38CoN2O4
• M. W.: 573.58832
• Purity: ≥97%

SYNONYMS

• Title: (1R,2R)-N,N′-双(2-乙酰-3-氧代-2-亚丁烯基)-1,2-二均三甲苯基乙二胺合钴(II)
• IUPAC name: 1-[(8R,9R)-12-acetyl-4,13-dimethyl-8,9-bis(2,4,6-trimethylphenyl)-1,3-dioxa-7,10-diaza-2-cobaltacyclotrideca-4,6,10,12-tetraen-5-yl]ethan-1-one
• IUPAC Traditional name: 1-[(8R,9R)-12-acetyl-4,13-dimethyl-8,9-bis(2,4,6-trimethylphenyl)-1,3-dioxa-7,10-diaza-2-cobaltacyclotrideca-4,6,10,12-tetraen-5-yl]ethanone
• Synonyms: (R,R)-AMAC

DATABASE IDS

• MDL Number: MFCD06797061
• CAS Number: 361346-80-7

PROPERTIES

• Empirical Formula (Hill Notation): C32H38CoN2O4
• Purity: ≥97%
• Melting Point: 246-250 °C
• Optical Rotation: [α]/D 291°, c = 0.1 in chloroform

DETAILS

Description (English)

Application
Catalyst used for the enantioselective reduction of ketones, hetero Diels-Alder reaction, carbonylene reaction, 1,3-dipolar cycloaddition9

• Schiff base-cobalt complex catalyst for asymmetric borohydride reduction of carbonyl compounds1Catalyst for:
• Enantioselective borohydride reduction2
• Stereoselective preparation of aryl alcohols via asymmetric reduction of aryl ketones with borohydride3
• Stereoselective borohydride reduction of diketones to diols4
• Stereoselective preparation of optically active deuterated primary alcohols via enantioselective borodeuteride reduction of aldehydes5
• Stereoselective preparation of β-hydroxy esters via dynamic kinetic resolution of alkylketo esters with enantioselective borohydride reduction6
• Chemoselective, diastereoselective, and enantioselective borohydride reduction of 1,3-diketones7
• Asymmetric synthesis of diarylhydroxypropanones by stereoselective reduction of alkyldiaryldiketones8
Packaging
100, 500 mg in glass bottle

Description (简体中文)

Application
酮类不对称还原反应、非均相 Diels-Alder 反应、羰基-烯反应、1,3-偶极环加成反应的催化剂9

• Schiff base-cobalt complex catalyst for asymmetric borohydride reduction of carbonyl compounds1Catalyst for:
• Enantioselective borohydride reduction2
• Stereoselective preparation of aryl alcohols via asymmetric reduction of aryl ketones with borohydride3
• Stereoselective borohydride reduction of diketones to diols4
• Stereoselective preparation of optically active deuterated primary alcohols via enantioselective borodeuteride reduction of aldehydes5
• Stereoselective preparation of β-hydroxy esters via dynamic kinetic resolution of alkylketo esters with enantioselective borohydride reduction6
• Chemoselective, diastereoselective, and enantioselective borohydride reduction of 1,3-diketones7
• Asymmetric synthesis of diarylhydroxypropanones by stereoselective reduction of alkyldiaryldiketones8
包装
100, 500 mg in glass bottle