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1,5-Cyclooctadiene{[dibenzyl((4S,5S)-5-methyl-2-phenyl-4,5-dihydro-4-oxazolyl)methyl]dicyclohexylphosphinite κN:κP}iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate_Molecular_structure_CAS_583844-38-6)
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1,5-Cyclooctadiene{[dibenzyl((4S,5S)-5-methyl-2-phenyl-4,5-dihydro-4-oxazolyl)methyl]dicyclohexylphosphinite κN:κP}iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate

Catalog No. 713678 Name Sigma Aldrich
CAS Number 583844-38-6 Website http://www.sigmaaldrich.com
M. F. C77H70BF24IrNO2P Telephone 1-800-521-8956
M. W. 1731.3486378 Fax
Purity 97% Email
Storage Chembase ID: 143026

SYNONYMS

IUPAC name
iridium(1+) ion 2-[(4R,5R)-5-methyl-2-phenyl-4,5-dihydro-1,3-oxazol-4-yl]-1,3-diphenylpropan-2-yl dicyclohexylphosphinite cycloocta-1,5-diene tetrakis[3,5-bis(trifluoromethyl)phenyl]boranuide
IUPAC Traditional name
iridium(1+) ion 1,5-cyclooctadiene 2-[(4R,5R)-5-methyl-2-phenyl-4,5-dihydro-1,3-oxazol-4-yl]-1,3-diphenylpropan-2-yl dicyclohexylphosphinite tetrakis[3,5-bis(trifluoromethyl)phenyl]boranuide
Synonyms
[((4S,5S)-Cy2-Ubaphox)Ir(COD)]BARF
Ubaphox

DATABASE IDS

CAS Number 583844-38-6
MDL Number MFCD06658139

PROPERTIES

Empirical Formula (Hill Notation) C77H70BF24IrNO2P
Optical Purity ee: ≥99%
Purity 97%
MSDS Link Download
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
German water hazard class 3

DETAILS

Description (English)
Application
Catalyst for enantioselective hydrogenation of alkenes1,2
General description
sold in collaboration with Solvias AG
Packaging
1, 5 g in glass bottle
100, 500 mg in glass bottle
Description (简体中文)
Application
Catalyst for enantioselective hydrogenation of alkenes1,2
General description
sold in collaboration with Solvias AG
包装
1, 5 g in glass bottle
100, 500 mg in glass bottle

REFERENCES