(R,R)-1,3-Bis[(4-bromophenyl)methyl]-2-chlorooctahydro-2-allyl-1H-1,3,2-benzodiazasilole

• Catalog No.: 704725
• CAS Number: 546084-25-7
• M. F.: C23H27Br2ClN2Si
• M. W.: 554.82038
• Purity: 95%

SYNONYMS

• Title: (R,R)-1,3-双[(4-溴苯基)甲基]-2-氯八氢-2-烯丙基-1H-1,3,2-苯并二氮杂噻咯
• IUPAC name: (3aR,7aR)-1,3-bis[(4-bromophenyl)methyl]-2-chloro-2-(prop-2-en-1-yl)-octahydro-1H-1,3,2-benzodiazasilole
• IUPAC Traditional name: (3aR,7aR)-1,3-bis[(4-bromophenyl)methyl]-2-chloro-2-(prop-2-en-1-yl)-hexahydro-1,3,2-benzodiazasilole
• Synonyms: (3aR,7aR)-2-烯丙基-1,3-双(4-溴苄基)-2-氯八氢-1H-苯并[d][1,3,2]二氮杂噻咯; (3aR,7aR)-2-Allyl-1,3-bis(4-bromobenzyl)-2-chlorooctahydro-1H-benzo[d][1,3,2]diazasilole

DATABASE IDS

• MDL Number: MFCD10567380
• CAS Number: 546084-25-7

PROPERTIES

• Empirical Formula (Hill Notation): C23H27Br2ClN2Si
• Purity: 95%
• Flash Point: >110 °C
• Flash Point: >230 °F
• Melting Point: 95-100 °C
• Optical Rotation: [α]22/D -53.0°, c = 1 in chloroform
• GHS Signal Word: Danger
• GHS Hazard statements: H261-H314
• European Hazard Symbols: Flammable (F)
• European Hazard Symbols: Corrosive (C)
• Personal Protective Equipment: Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
• GHS Precautionary statements: P231 + P232-P280-P305 + P351 + P338-P310-P422
• RID/ADR: UN 3131 4.3/PG 3
• Risk Statements: 15-34
• Safety Statements: 26-36/37/39-43-45
• Storage Temperature: 2-8°C
• Hazard Class: 4.3
• UN Number: 3131
• Packing Group: 3
• German water hazard class: 1

DETAILS

Description (English)

Application
An operationally simple regioselective and enantioselective allylation of beta-diketones to provide tertiary carbinols3
Leighton’s Strained Silacycles: Powerful Enantioselective Allylation Reagents
• Enantioselective allylation of aldehydes1,2
Packaging
1, 5 g in glass bottle
Legal Information
U.S. Patent No. 7,534,905

Description (简体中文)

Application
An operationally simple regioselective and enantioselective allylation of beta-diketones to provide tertiary carbinols3
Leighton’s Strained Silacycles: Powerful Enantioselective Allylation Reagents
• Enantioselective allylation of aldehydes1,2
包装
1, 5 g in glass bottle
Legal Information
美国专利号 7,534,905