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1,1′-Bis(dichlorophosphino)ferrocene_Molecular_structure_CAS_142691-70-1)
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1,1′-Bis(dichlorophosphino)ferrocene

Catalog No. 698555 Name Sigma Aldrich
CAS Number 142691-70-1 Website http://www.sigmaaldrich.com
M. F. C10H8Cl4FeP2 Telephone 1-800-521-8956
M. W. 387.775042 Fax
Purity ≥96% Email
Storage Chembase ID: 142859

SYNONYMS

Title
1,1′-双(二氯磷)二茂铁
IUPAC name
λ2-iron(2+) ion bis(3-(dichlorophosphanyl)cyclopenta-2,4-dien-1-ide)
IUPAC Traditional name
λ2-iron(2+) ion bis(3-(dichlorophosphanyl)cyclopenta-2,4-dien-1-ide)

DATABASE IDS

CAS Number 142691-70-1
MDL Number MFCD01630854

PROPERTIES

Empirical Formula (Hill Notation) C10H8Cl4FeP2
Purity ≥96%
Melting Point 67-71 °C
GHS Pictograms GHS05
GHS Signal Word Danger
GHS Hazard statements H314
European Hazard Symbols Corrosive Corrosive (C)
MSDS Link Download
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
GHS Precautionary statements P280-P305 + P351 + P338-P310
RID/ADR UN 1759 8/PG 2
Risk Statements 34
Safety Statements 26-36/37/39-45
Hazard Class 8
UN Number 1759
Packing Group 2
German water hazard class 3

DETAILS

Description (English)
Packaging
250 mg in glass bottle
Application
Reactant for synthesis of:
• Ferrocene-based bidentate phosphonite ligands for rhodium(I)-catalyzed enantioselective hydroformylation1
• Metallocene-bridged bisphosphaalkene2Catalyst for synthesis of oligonuclear heterometallic complexes3
Description (简体中文)
包装
250 mg in glass bottle
Application
Reactant for synthesis of:
• Ferrocene-based bidentate phosphonite ligands for rhodium(I)-catalyzed enantioselective hydroformylation1
• Metallocene-bridged bisphosphaalkene2Catalyst for synthesis of oligonuclear heterometallic complexes3

REFERENCES