Bis(4-methoxyphenyl)chlorophosphine

• Catalog No.: 710377
• CAS Number: 13685-30-8
• M. F.: C14H14ClO2P
• M. W.: 280.686521
• Purity: 85%

SYNONYMS

• Title: 双(4-甲氧基苯基)氯化膦
• IUPAC name: chlorobis(4-methoxyphenyl)phosphane
• IUPAC Traditional name: chlorobis(4-methoxyphenyl)phosphane
• Synonyms: P,P-Bis(4-methoxyphenyl)phosphinous chloride

DATABASE IDS

• CAS Number: 13685-30-8
• MDL Number: MFCD04972301

PROPERTIES

• Empirical Formula (Hill Notation): C14H14ClO2P
• Purity: 85%
• Melting Point: 62-66 °C
• GHS Signal Word: Danger
• GHS Hazard statements: H314
• European Hazard Symbols: Corrosive (C)
• Personal Protective Equipment: Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
• GHS Precautionary statements: P280-P305 + P351 + P338-P310
• RID/ADR: UN 3261 8/PG 2
• Risk Statements: 34
• Safety Statements: 26-36/37/39-45
• Hazard Class: 8
• UN Number: 3261
• Packing Group: 2
• German water hazard class: 3

DETAILS

Description (English)

Packaging
2 g in glass bottle
Application
Reactant for asymmetric:
• Allylic substitution1
• Intermolecular Pauson-Khand reaction of symmetrically substituted alkynes2
• Hydrogenation3
• Intramolecular α-arylation of aldehydes4Reactant for:
• Alcoholysis of phosphane-boranes5
• Probing hemilabile sites of Bis(phosphine) monoxide ligands6

Description (简体中文)

包装
2 g in glass bottle
Application
Reactant for asymmetric:
• Allylic substitution1
• Intermolecular Pauson-Khand reaction of symmetrically substituted alkynes2
• Hydrogenation3
• Intramolecular α-arylation of aldehydes4Reactant for:
• Alcoholysis of phosphane-boranes5
• Probing hemilabile sites of Bis(phosphine) monoxide ligands6