Pentacene-N-sulfinyl-tert-butylcarbamate

• Catalog No.: 699306
• CAS Number: 794586-44-0
• M. F.: C27H23NO3S
• M. W.: 441.54142
• Purity: 99% (HPLC)

SYNONYMS

• Title: 并五苯-N-亚磺酰基-氨基甲酸叔丁酯
• IUPAC name: tert-butyl 23-oxo-23λ^4-thia-24-azahexacyclo[10.10.2.0^2,^1^1.0^4,^9.0^1^3,^2^2.0^1^5,^2^0]tetracosa-2(11),3,5,7,9,13(22),14,16,18,20-decaene-24-carboxylate
• IUPAC Traditional name: tert-butyl 23-oxo-23λ^4-thia-24-azahexacyclo[10.10.2.0^2,^1^1.0^4,^9.0^1^3,^2^2.0^1^5,^2^0]tetracosa-2(11),3,5,7,9,13(22),14,16,18,20-decaene-24-carboxylate
• Synonyms: 可光致图案的可溶性并五苯前体; 13,6-(Epithioimino)pentacene-16-carboxylic acid, 6,13-dihydro-, tert butyl ester, 15-oxide

DATABASE IDS

• CAS Number: 794586-44-0

PROPERTIES

• Empirical Formula (Hill Notation): C27H23NO3S
• Purity: 99% (HPLC)
• Melting Point: >300 °C
• Solubility: THF: soluble1 mg/mL
• Solubility: ethanol: slightly soluble1 mg/mL
• Solubility: isopropanol: slightly soluble1 mg/mL
• Solubility: methanol: slightly soluble1 mg/mL
• GHS Signal Word: Warning
• GHS Hazard statements: H400
• European Hazard Symbols: Nature polluting (N)
• Personal Protective Equipment: Eyeshields, Gloves
• GHS Precautionary statements: P273
• RID/ADR: UN 3077 9/PG 3
• Risk Statements: 50/53
• Safety Statements: 60-61
• Hazard Class: 9
• UN Number: 3077
• Packing Group: 3
• German water hazard class: 3

DETAILS

Description (English)

Application
Photopatternable pentacene precursor highly solube in apolar organic solvents (halogenated solvents, THF). Converted to pentacene in thin (e.g. spin-cast) films by heating under N2 atmosphere for one hour at 150 °C. Spin-coated thin films of the pentacene precursor can be patterned by exposure to UV light in the presence of a photoacid generator (e.g. 531014), followed by a brief heating (5 min. at 130 °C and washing away of an un-converted precursor. Organic thin film transistors fabricated by solution processing of this precursor showed mobilities of 0.13 cm2V-1s-1 and on/off ratio 2 x 105.1
Packaging
100, 500 mg in poly bottle
Protocols & Applications
Fabrication of Organic Field Effect Transistor Device Using a Soluble Pentacene Precursor

Description (简体中文)

Application
极易溶于非极性有机溶剂（卤化溶剂，THF）的可光致图案并五苯前体。在薄（如旋铸）膜中通过在 150°C 和 N2 下加热 1 小时可转化成并五苯。可通过在光酸产生剂（如 531014）存在下暴露于紫外线，然后进行短暂的加热（130°C 下 5 分钟）并洗掉未转化的前体，而将旋涂的并五苯前体薄膜图案化。通过该前体的溶液加工制造的有机薄膜晶体管表现出 0.13cm2V-1s-1 的迁移率和 2×105 的开关比。1
包装
100, 500 mg in poly bottle
Protocols & Applications
Fabrication of Organic Field Effect Transistor Device Using a Soluble Pentacene Precursor