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1,3-Bis(2,4,6-trimethylphenyl)imidazolinium chloride_Molecular_structure_CAS_173035-10-4)
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1,3-Bis(2,4,6-trimethylphenyl)imidazolinium chloride

Catalog No. 656631 Name Sigma Aldrich
CAS Number 173035-10-4 Website http://www.sigmaaldrich.com
M. F. C21H27ClN2 Telephone 1-800-521-8956
M. W. 342.90548 Fax
Purity 95% Email
Storage Chembase ID: 142800

SYNONYMS

Title
1,3-双(2,4,6-三甲基苯基)氯化咪唑
IUPAC name
1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydro-3H-1λ5,3-imidazol-1-ylium chloride
IUPAC Traditional name
1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydro-1λ5,3-imidazol-1-ylium chloride
Synonyms
1,3-二(2,4,6-三甲苯)咪唑氯盐
1,3-Dimesitylimidazolidinium chloride
4,5-Dihydro-1,3-dimesityl-1H-imidazolium chloride
4,5-Dihydro-1,3-bis(2,4,6-trimethylphenyl)-1H-imidazolium chloride
N,N′-(2,4,6-Trimethylphenyl)dihydroimidazolium chloride

DATABASE IDS

PubChem SID 24884213
MDL Number MFCD09039279
CAS Number 173035-10-4

PROPERTIES

Empirical Formula (Hill Notation) C21H27ClN2
Purity 95%
Melting Point 280-286 °C
GHS Pictograms GHS07
GHS Signal Word Warning
GHS Hazard statements H315-H319-H335
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P261-P305 + P351 + P338
Risk Statements 36/37/38
Safety Statements 26-36
German water hazard class 3

DETAILS

Description (English)
Packaging
1, 5 g in glass bottle
Application
N-Heterocyclic Carbene Ligands Precursor to an N-heterocyclic carbene catalysts used for:
• A regioselective cycloadditon of terminal acetylenes with azides leading to 1,4-disubstitutedtriazoles. Internal acetylenes can also be used with this catalyst.1
• Markovnikov-type hydration of terminal alkynes2
• Hydrosilylation of ketones and cycloaddition of azides and alkynes3
• Suzuki-Miyaura reactions4
• Luminescence experiments5
Description (简体中文)
包装
1, 5 g in glass bottle
Application
N-Heterocyclic Carbene Ligands Precursor to an N-heterocyclic carbene catalysts used for:
• A regioselective cycloadditon of terminal acetylenes with azides leading to 1,4-disubstitutedtriazoles. Internal acetylenes can also be used with this catalyst.1
• Markovnikov-type hydration of terminal alkynes2
• Hydrosilylation of ketones and cycloaddition of azides and alkynes3
• Suzuki-Miyaura reactions4
• Luminescence experiments5

REFERENCES