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4-Amino-3-iodobenzonitrile_Molecular_structure_CAS_33348-34-4)
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4-Amino-3-iodobenzonitrile

Catalog No. 657123 Name Sigma Aldrich
CAS Number 33348-34-4 Website http://www.sigmaaldrich.com
M. F. C7H5IN2 Telephone 1-800-521-8956
M. W. 244.03247 Fax
Purity 98% Email
Storage Chembase ID: 142784

SYNONYMS

Title
4-氨基-3-碘苯腈
IUPAC name
4-amino-3-iodobenzonitrile
IUPAC Traditional name
4-amino-3-iodobenzonitrile
Synonyms
4-氨基-3-碘苯甲腈
1-Amino-2-iodo-4-cyanobenzene
4-Cyano-2-iodoaniline

DATABASE IDS

MDL Number MFCD04039964
PubChem SID 24884265
CAS Number 33348-34-4

PROPERTIES

Risk Statements 36/37/38
Safety Statements 26-36
German water hazard class 3
GHS Pictograms GHS07
GHS Signal Word Warning
GHS Hazard statements H315-H319-H335
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
GHS Precautionary statements P261-P305 + P351 + P338
Linear Formula IC6H3(NH2)CN
Purity 98%
Melting Point 112-115 °C(lit.)

DETAILS

Description (English)
Application
Palladium-catalyzed carbonylation of iodoanilines provides ketoamides in the presence of primary and secondary amines.8
Reactant involved in:
• Hydroamination-double hydroarylation for synthesis of fuzed carbazoles1
• Cycloisomerizations of aromatic homo- and bis-homopropargylic amine / amide intermediates2
• Asymmetric organocatalytic condensation and cycloaddition3
• Regioselective aryl C-H bond functionalization4
• Synthesis of [(triisopropylsilyl)ethynyl]indole derivatives5
• Domino condensation / S-arylation / heterocyclization reactions6,7
Packaging
1, 5 g in glass bottle
Description (简体中文)
Application
在伯胺和仲胺存在的条件下,碘苯胺可经钯催化发生羰基化反应,生成酮酰胺。8
Reactant involved in:
• Hydroamination-double hydroarylation for synthesis of fuzed carbazoles1
• Cycloisomerizations of aromatic homo- and bis-homopropargylic amine / amide intermediates2
• Asymmetric organocatalytic condensation and cycloaddition3
• Regioselective aryl C-H bond functionalization4
• Synthesis of [(triisopropylsilyl)ethynyl]indole derivatives5
• Domino condensation / S-arylation / heterocyclization reactions6,7
包装
1, 5 g in glass bottle

REFERENCES