Home > Compound List > Product Information
(1S,2S)-N,N′-Dihydroxy-N,N′-bis(bis(3,5-dimethylphenyl)acetyl)-1,2-cyclohexanediamine_Molecular_structure_CAS_1217463-44-9)
Click picture or here to close

(1S,2S)-N,N′-Dihydroxy-N,N′-bis(bis(3,5-dimethylphenyl)acetyl)-1,2-cyclohexanediamine

Catalog No. 700568 Name Sigma Aldrich
CAS Number 1217463-44-9 Website http://www.sigmaaldrich.com
M. F. C42H50N2O4 Telephone 1-800-521-8956
M. W. 646.8574 Fax
Purity 97% Email
Storage Chembase ID: 142712

SYNONYMS

Title
(1S,2S)-N,N′-二羟基-N,N′-双(双(3,5-二甲苯基)乙酰基)-1,2-环己二胺
IUPAC name
N-[(1S,2S)-2-[2,2-bis(3,5-dimethylphenyl)-N-hydroxyacetamido]cyclohexyl]-2,2-bis(3,5-dimethylphenyl)-N-hydroxyacetamide
IUPAC Traditional name
N-[(1S,2S)-2-[2,2-bis(3,5-dimethylphenyl)-N-hydroxyacetamido]cyclohexyl]-2,2-bis(3,5-dimethylphenyl)-N-hydroxyacetamide
Synonyms
(1S,2S)-N,N′-二羟基-N,N′-双(3,5-二甲基二苯基乙酰基)-环己烷-二胺
N,N′-(1S,2S)-1,2-环己二基双[α-(3,5-二甲苯基)-N-羟基-3,5-二甲基苯乙酰胺]
(S)-CBHA-DMDA
N,N′-(1S,2S)-1,2-cyclohexanediylbis[α-(3,5-dimethylphenyl)-N-hydroxy-3,5-dimethylbenzeneacetamide]
(1S,2S)-N,N′-Dihydroxy-N,N′-bis(3,5-dimethyldiphenylacetyl)-cyclohexane-diamine

DATABASE IDS

CAS Number 1217463-44-9

PROPERTIES

Empirical Formula (Hill Notation) C42H50N2O4
Purity 97%
Melting Point 186-190 °C
Optical Rotation [α]22/D -76°, c = 1 in chloroform
GHS Pictograms GHS06
GHS Signal Word Danger
GHS Hazard statements H300
European Hazard Symbols Toxic Toxic (T)
MSDS Link Download
Personal Protective Equipment Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
GHS Precautionary statements P264-P301 + P310
RID/ADR UN 2811 6.1/PG 3
Risk Statements 25
Safety Statements 45
Hazard Class 6.1
UN Number 2811
Packing Group 3
German water hazard class 3

DETAILS

Description (English)
Application
Ligand used with vanadium for asymmetric epoxidation of allylic alcohols1,2
Packaging
50 mg in glass bottle
Protocols & Applications
Asymmetric Oxidation with CHBA Ligands
Asymmetric Epoxidation of Allylic Alcohols
Asymmetric Epoxidation of Homoallylic Alcohols
Asymmetric Ketone Hydrogenation
Asymmetric Transfer Hydrogenation
Description (简体中文)
Application
与钒共同用于烯丙醇的不对称环氧化反应的配体1,2
包装
50 mg in glass bottle
Protocols & Applications
Asymmetric Oxidation with CHBA Ligands
Asymmetric Epoxidation of Allylic Alcohols
Asymmetric Epoxidation of Homoallylic Alcohols
Asymmetric Ketone Hydrogenation
Asymmetric Transfer Hydrogenation

REFERENCES