(1R,2R)-N,N′-Dihydroxy-N,N′-bis(3,3,3-triphenylpropionyl)-1,2-cyclohexanediamine

• Catalog No.: 700541
• CAS Number: 860036-29-9
• M. F.: C48H46N2O4
• M. W.: 714.88984
• Purity: 95%

SYNONYMS

• Title: (1R,2R)-N,N′-二羟基-N,N′-双(3,3,3-三苯基丙酰)-环己烷-1,2-二胺
• IUPAC name: N-hydroxy-N-[(1R,2R)-2-(N-hydroxy-3,3,3-triphenylpropanamido)cyclohexyl]-3,3,3-triphenylpropanamide
• IUPAC Traditional name: N-hydroxy-N-[(1R,2R)-2-(N-hydroxy-3,3,3-triphenylpropanamido)cyclohexyl]-3,3,3-triphenylpropanamide
• Synonyms: N,N′-(1R,2R)-1,2-cyclohexanediylbis[N-hydroxy-β,β-diphenylbenzenepropanamide]; (R)-CBHA-TPP; (1R,2R)-N,N′-Dihydroxy-N,N′-bis(triphenylpropionyl)-cyclohexane-1,2-diamine; (1R,2R)-N,N′-二羟基-N,N′-双(三苯基丙酰)-1,2-环己二胺; N,N′-(1R,2R)-1,2-环己二基双[N-羟基-β,β-二苯基苯丙酰胺]

DATABASE IDS

• MDL Number: MFCD11044407
• CAS Number: 860036-29-9

PROPERTIES

• Empirical Formula (Hill Notation): C48H46N2O4
• Purity: 95%
• Melting Point: 217-221 °C
• Optical Rotation: [α]22/D +22.0±5°, c = 1 in chloroform
• Personal Protective Equipment: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• Storage Temperature: 2-8°C
• German water hazard class: 3

DETAILS

Description (English)

Application
Ligand used with vanadium for asymmetric epoxidation of allylic alcohols1,2
Packaging
50 mg in glass bottle
Protocols & Applications
Asymmetric Oxidation with CHBA Ligands
Asymmetric Epoxidation of Allylic Alcohols
Asymmetric Epoxidation of Homoallylic Alcohols
Asymmetric Ketone Hydrogenation
Asymmetric Transfer Hydrogenation

Description (简体中文)

Application
与钒共同用于烯丙醇的不对称环氧化反应的配体1,2
包装
50 mg in glass bottle
Protocols & Applications
Asymmetric Oxidation with CHBA Ligands
Asymmetric Epoxidation of Allylic Alcohols
Asymmetric Epoxidation of Homoallylic Alcohols
Asymmetric Ketone Hydrogenation
Asymmetric Transfer Hydrogenation