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(Bis-((4S,4′S)-tert-butylphenyl)-4,5-dihydro-2-oxazolyl)acetonitrileoxo(dichlorotriphenylphosphine oxide)rhenium(V)_Molecular_structure_CAS_)
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(Bis-((4S,4′S)-tert-butylphenyl)-4,5-dihydro-2-oxazolyl)acetonitrileoxo(dichlorotriphenylphosphine oxide)rhenium(V)

Catalog No. 706353 Name Sigma Aldrich
CAS Number Website http://www.sigmaaldrich.com
M. F. C46H47Cl2N3O4PRe Telephone 1-800-521-8956
M. W. 993.969841 Fax
Purity Email
Storage Chembase ID: 142702

SYNONYMS

Title
(双-((4S,4′S)-叔丁基苯基)-4,5-二氢-2-噁唑基)乙腈氧代(二氯三苯基磷化氧化物)铼(V)
IUPAC name
bis[4-(4-tert-butylphenyl)-4,5-dihydro-1,3-oxazol-2-yl](cyano)methylium triphenylphosphane dichlororheniumoylolate
IUPAC Traditional name
bis[4-(4-tert-butylphenyl)-4,5-dihydro-1,3-oxazol-2-yl](cyano)methylium triphenylphosphane dichlororheniumoylolate

DATABASE IDS

PROPERTIES

Empirical Formula (Hill Notation) C46H47Cl2N3O4PRe
Melting Point 266-279 °C
GHS Pictograms GHS07
GHS Signal Word Warning
GHS Hazard statements H315-H319-H335
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
GHS Precautionary statements P261-P305 + P351 + P338
Risk Statements 36/37/38
Safety Statements 26
Storage Temperature 2-8°C
German water hazard class 2

DETAILS

Description (English)
Application
Catalyst for the highly enantioselective reduction of phosphinyl imines in the presence of dimethylphenylsilane as the hydrogen source.1
Packaging
100 mg in glass bottle
Description (简体中文)
Application
用于在二甲基苯基硅烷作为氢源存在的情况下氧膦基亚胺高度不对称还原的催化剂。1
包装
100 mg in glass bottle

REFERENCES