Bis(4-methylphenyl)chlorophosphine

• Catalog No.: 695815
• CAS Number: 1019-71-2
• M. F.: C14H14ClP
• M. W.: 248.687721
• Purity: 96%

SYNONYMS

• Title: 双(4-甲基苯基)氯膦
• IUPAC name: chlorobis(4-methylphenyl)phosphane
• IUPAC Traditional name: chlorobis(4-methylphenyl)phosphane
• Synonyms: P,P-Bis(4-methylphenyl)-phosphinous chloride; P,P-双(4-甲基苯基)-氯化膦; Chlorodi-p-tolylphosphine; 氯二对甲苯基膦

DATABASE IDS

• MDL Number: MFCD01630844
• CAS Number: 1019-71-2

PROPERTIES

• Empirical Formula (Hill Notation): C14H14ClP
• Purity: 96%
• Density: 1.1 g/mL at 25 °C
• Refractive Index: n20/D 1.501
• GHS Signal Word: Danger
• GHS Hazard statements: H314
• European Hazard Symbols: Corrosive (C)
• Personal Protective Equipment: Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• GHS Precautionary statements: P280-P305 + P351 + P338-P310
• RID/ADR: UN 3265 8/PG 3
• Risk Statements: 14-34
• Safety Statements: 26-36/37/39-45
• Supplemental Hazard Statements: Reacts violently with water.
• Hazard Class: 8
• UN Number: 3265
• Packing Group: 3
• German water hazard class: 3

DETAILS

Description (简体中文)

包装
1 g in glass bottle
250 mg in glass bottle
Application
Reactant for synthesis of:
• Palladium catalysts for C-C bond forming cross-coupling reactions1
• Ligands for nickel(0)-catalyzed isomerization reactions2
• Phosphinosulfonamide nickel complexes for oligomerization reactions3Reactant for:
• Pd-catalyzed intramolecular asymmetric allylic amination and ring-closing metathesis4
• Phosphinylation reactions5

Description (English)

Packaging
1 g in glass bottle
250 mg in glass bottle
Application
Reactant for synthesis of:
• Palladium catalysts for C-C bond forming cross-coupling reactions1
• Ligands for nickel(0)-catalyzed isomerization reactions2
• Phosphinosulfonamide nickel complexes for oligomerization reactions3Reactant for:
• Pd-catalyzed intramolecular asymmetric allylic amination and ring-closing metathesis4
• Phosphinylation reactions5