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Lithium pyrrolidinoborohydride solution_Molecular_structure_CAS_144188-76-1)
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Lithium pyrrolidinoborohydride solution

Catalog No. 658243 Name Sigma Aldrich
CAS Number 144188-76-1 Website http://www.sigmaaldrich.com
M. F. C4H10BLiN Telephone 1-800-521-8956
M. W. 89.8809 Fax
Purity Email
Storage Chembase ID: 142613

SYNONYMS

Title
吡咯烷并硼氢化锂 溶液
IUPAC name
lithium(1+) ion pyrrolidin-1-ylboranuide
IUPAC Traditional name
lithium(1+) ion pyrrolidin-1-ylboranuide
Synonyms
三氢-1-吡咯烷基硼酸锂
Lithium trihydro-1-pyrrolidinylborate

DATABASE IDS

MDL Number MFCD07784405
CAS Number 144188-76-1
PubChem SID 24884339

PROPERTIES

Safety Statements 16-26
Storage Temperature 2-8°C
Supplemental Hazard Statements May form explosive peroxides.
Hazard Class 4.3
UN Number 3399
Packing Group 1
German water hazard class 3
GHS Pictograms GHS02
GHS Pictograms GHS07
GHS Signal Word Danger
GHS Hazard statements H225-H319-H335
European Hazard Symbols Flammable Flammable (F)
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
GHS Precautionary statements P210-P261-P305 + P351 + P338
RID/ADR UN 3399 4.3/PG 1
Risk Statements 11-19-36/37
Concentration 1 M in THF
Empirical Formula (Hill Notation) C4H11BLiN
Density 0.890 g/mL at 25 °C
Flash Point -17 °C
Flash Point 1.4 °F
Refractive Index n20/D 1.425

DETAILS

Description (English)
Application
Capable of reducing a variety of fuctional groups.3,4,5,4
LABs can transfer the amine moiety, as in the case of the reaction with halopyridines and primary alkyl methanesulfonates.
Lithium Aminoborohydride (LAB) Reagents
• Reducing agent for reduction of carbonic and carboxylic acid derivatives1
• Reagent for reduction-amination reactions2
Packaging
25, 100 mL in Sure/Seal™
Description (简体中文)
Application
在与卤代吡啶类化合物和伯烷基甲磺酸酯类化合物反应的情况下,LAB 可以转移胺部分。
能够还原各种官能团。3,4,5,4
Lithium Aminoborohydride (LAB) Reagents
• Reducing agent for reduction of carbonic and carboxylic acid derivatives1
• Reagent for reduction-amination reactions2
包装
25, 100 mL in Sure/Seal™

REFERENCES