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Lithium dimethylaminoborohydride solution_Molecular_structure_CAS_53042-33-4)
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Lithium dimethylaminoborohydride solution

Catalog No. 658235 Name Sigma Aldrich
CAS Number 53042-33-4 Website http://www.sigmaaldrich.com
M. F. C2H8BLiN Telephone 1-800-521-8956
M. W. 63.84362 Fax
Purity Email
Storage Chembase ID: 142611

SYNONYMS

Title
二甲氨基硼氢化锂 溶液
IUPAC name
lithium(1+) ion (dimethylamino)boranuide
IUPAC Traditional name
lithium(1+) ion (dimethylamino)boranuide
Synonyms
N-甲基甲胺硼络合物
(二甲氨基)三氢硼酸锂
Lithium trihydro(N-methylmethanaminato)borate
N-Methylmethanamine boron complex
Lithium (dimethylamino)trihydroborate

DATABASE IDS

PubChem SID 24884338
CAS Number 53042-33-4
MDL Number MFCD07784404

PROPERTIES

Concentration 1 M in THF
Empirical Formula (Hill Notation) C2H9BLiN
Density 0.882 g/mL at 25 °C
Flash Point -17 °C
Flash Point 0 °F
Refractive Index n20/D 1.423
European Hazard Symbols Flammable Flammable (F)
European Hazard Symbols Corrosive Corrosive (C)
MSDS Link Download
RID/ADR UN 3399 4.3/PG 1
Risk Statements 11-14/15-19-34
Safety Statements 16-26-29-33-36/37/39-43.4-45
Storage Temperature 2-8°C
Hazard Class 4.3
UN Number 3399
Packing Group 1
German water hazard class 1

DETAILS

Description (English)
Application
Capable of reducing a variety of fuctional groups.5,6,7,6
LABs can transfer the amine moiety, as in the case of the reaction with halopyridines and primary alkyl methanesulfonates.
Lithium Aminoborohydride (LAB) ReagentsReactant for:
• B-H oxidative addition reactions1
• Reduction and amination reactions2
• Reduction of N-alkyl lactams3
• Synthesis of tertiary amine-boranes4
Packaging
25, 100 mL in Sure/Seal™
Description (简体中文)
Application
在与卤代吡啶和伯烷基甲磺酸酯反应的情况下,LAB 可以转移胺部分。
能够还原各种官能团。5,6,7,6
Lithium Aminoborohydride (LAB) ReagentsReactant for:
• B-H oxidative addition reactions1
• Reduction and amination reactions2
• Reduction of N-alkyl lactams3
• Synthesis of tertiary amine-boranes4
包装
25, 100 mL in Sure/Seal™

REFERENCES