(S,S′,R,R′)-TangPhos-rhodium complex

• Catalog No.: 659703
• M. F.: C24H44BF4P2Rh
• M. W.: 584.2637948

SYNONYMS

• Title: (S,S′,R,R′)-TangPhos-铑络合物
• IUPAC name: λ^1-rhodium(1+) ion (2R)-1-tert-butyl-2-[(2R)-1-tert-butylphospholan-2-yl]phospholane cycloocta-1,5-diene tetrafluoroboranuide
• IUPAC Traditional name: λ^1-rhodium(1+) ion (2R)-1-tert-butyl-2-[(2R)-1-tert-butylphospholan-2-yl]phospholane 1,5-cyclooctadiene tetrafluoroborate
• Synonyms: (S,S′,R,R′)-TangPhos(环辛二烯)四氟硼酸铑(I); (S,S′,R,R′)-TangPhos(cyclooctadiene)rhodium(I) tetrafluoroborate

DATABASE IDS

• MDL Number: MFCD07782006
• PubChem SID: 24884438

PROPERTIES

• Empirical Formula (Hill Notation): C24H44BF4P2Rh
• Melting Point: >300 °C
• Personal Protective Equipment: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• German water hazard class: 3

DETAILS

Description (English)

Application
Highly efficient in rhodium-catalyzed hydrogenation of α-dehyroamino acids and α-arylenamides,1 β-(acylamino)acrylates,2 itaconic acids, and enol acetates.3 Also gives outstanding enantioselectivities in asymmetric hydroformylation reactions.4
Chiral Quest Phosphine Ligands for Asymmetric Hydrogenation
Packaging
100, 500 mg in glass bottle

Description (简体中文)

Application
在 α-脱氢氨基酸、α-芳基烯酰胺、1β-(酰胺基)丙烯酸酯、2衣康酸以及乙酸烯醇酯的铑催化氢化中具有高效性。3也能在不对称加氢甲酰化反应中提供出色的对映选择性。4
Chiral Quest Phosphine Ligands for Asymmetric Hydrogenation
包装
100, 500 mg in glass bottle