(R,R)-ANDEN-Phenyl Trost Ligand

• Catalog No.: 697591
• CAS Number: 152140-65-3
• M. F.: C54H42N2O2P2
• M. W.: 812.871002

SYNONYMS

• Title: (R,R)-ANDEN-苯基 Trost 配体
• IUPAC name: 2-(diphenylphosphanyl)-N-[(1S,8S,15R,16R)-16-[2-(diphenylphosphanyl)benzamido]tetracyclo[6.6.2.0^2,^7.0^9,^1^4]hexadeca-2(7),3,5,9(14),10,12-hexaen-15-yl]benzamide
• IUPAC Traditional name: 2-(diphenylphosphanyl)-N-[(1S,8S,15R,16R)-16-[2-(diphenylphosphanyl)benzamido]tetracyclo[6.6.2.0^2,^7.0^9,^1^4]hexadeca-2(7),3,5,9(14),10,12-hexaen-15-yl]benzamide
• Synonyms: (+)-(11R,12R)Bis[2′-(diphenylphosphino)benzamido]-9,10-dihydro-9,10-ethanoanthracene; (+)-(11R,12R)双[2′-(二苯基膦)苯甲酰氨基]-9,10-二氢-9,10-乙基桥蒽; (11R,12R)-N,N′-(9,10-二氢-9,10-乙基桥蒽-11,12-二基)双[2-(二苯基膦)]-苯甲酰胺; (11R,12R)-N,N′-(9,10-Dihydro-9,10-ethanoanthracene-11,12-diyl)bis[2-(diphenylphosphino)]benzamide

DATABASE IDS

• MDL Number: MFCD12546007
• CAS Number: 152140-65-3

PROPERTIES

• Empirical Formula (Hill Notation): C54H42N2O2P2
• Grade: technical grade
• Melting Point: 125-130 °C
• Optical Rotation: [α]22/D -100°, c = 1 in chloroform
• Personal Protective Equipment: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• German water hazard class: 3

DETAILS

Description (English)

Application
Asymmetric allylic alkylation ligand.4,5,6,7
Catalyst involved in asymmetric allylic alkylations1,2,3
Packaging
100, 500 mg in glass bottle
Legal Information
Sold in collaboration with Dr. Reddy′s Laboratories for research purposes only. US Patent 5739396 applies.

Description (简体中文)

Application
不对称烯丙基烷化反应的配体4,5,6,7。
Catalyst involved in asymmetric allylic alkylations1,2,3
包装
100, 500 mg in glass bottle
Legal Information
与 Dr. Reddy′s Laboratories 合作销售，仅供研究使用。适用美国专利 5739396。