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1,3-Bis-(2,6-diisopropylphenyl)-[1,3,2]diazaphospholidine 2-oxide_Molecular_structure_CAS_854929-36-5)
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1,3-Bis-(2,6-diisopropylphenyl)-[1,3,2]diazaphospholidine 2-oxide

Catalog No. 708275 Name Sigma Aldrich
CAS Number 854929-36-5 Website http://www.sigmaaldrich.com
M. F. C26H39N2OP Telephone 1-800-521-8956
M. W. 426.574421 Fax
Purity 97% Email
Storage Chembase ID: 142544

SYNONYMS

Title
1,3-双-(2,6-二异丙基苯基)-[1,3,2]二氮杂磷啶 2-氧化物
IUPAC name
1,3-bis[2,6-bis(propan-2-yl)phenyl]-1,3,2λ5-diazaphospholidin-2-one
IUPAC Traditional name
1,3-bis(2,6-diisopropylphenyl)-1,3,2λ5-diazaphospholidin-2-one
Synonyms
1,3-Bis[2,6-bis(1-methylethyl)phenyl]-1,3,2-diazaphospholidine 2-oxide

DATABASE IDS

MDL Number MFCD14708169
CAS Number 854929-36-5

PROPERTIES

Empirical Formula (Hill Notation) C26H39N2OP
Purity 97%
Melting Point 205-210 °C
MSDS Link Download
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
German water hazard class 2

DETAILS

Description (English)
Application
Ligand used with ruthenium for dehydrative direct arylation of arenes with phenols2
Reactnat for synthesis of air-stable palladium HASPO complexes1Catalyst for:
• Dehydrative direct arylations of arenes2
• Aryl-(hetero)aryl coupling by activation of C-Cl and C-F bonds3
Packaging
1 g in glass bottle
250 mg in glass bottle
Description (简体中文)
Application
与钌共同用于芳烃与酚脱水直接芳基化的配体2
Reactnat for synthesis of air-stable palladium HASPO complexes1Catalyst for:
• Dehydrative direct arylations of arenes2
• Aryl-(hetero)aryl coupling by activation of C-Cl and C-F bonds3
包装
1 g in glass bottle
250 mg in glass bottle

REFERENCES