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Dichloro(tricyclohexylphosphine)[(tricyclohexylphosphoranyl)methylidene]ruthenium(II) tetrafluoroborate_Molecular_structure_CAS_1020085-61-3)
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Dichloro(tricyclohexylphosphine)[(tricyclohexylphosphoranyl)methylidene]ruthenium(II) tetrafluoroborate

Catalog No. 707961 Name Sigma Aldrich
CAS Number 1020085-61-3 Website http://www.sigmaaldrich.com
M. F. C37H67BCl2F4P2Ru Telephone 1-800-521-8956
M. W. 832.6560148 Fax
Purity 95% Email
Storage Chembase ID: 142530

SYNONYMS

Title
二氯(三环己基膦)[(三环己基正膦基)亚甲基]四氟硼酸钌(II)
IUPAC name
tetrafluoroboranuide; tricyclohexyl[(dichlororutheniumylidene)methyl]phosphanium; tricyclohexylphosphane
IUPAC Traditional name
tricyclohexyl[(dichlororutheniumylidene)methyl]phosphanium tricyclohexylphosphine tetrafluoroborate
Synonyms
Piers first generation metathesis catalyst
Dichloro(PCy3)[(tricyclohexylphosphoranyl)methylidene]Ru tetrafluoroborate
Piers 第一代复分解反应催化剂

DATABASE IDS

MDL Number MFCD15144782
CAS Number 1020085-61-3

PROPERTIES

Empirical Formula (Hill Notation) C37H67BCl2F4P2Ru
Purity 95%
Melting Point 203 °C (dec.)
GHS Pictograms GHS02
GHS Signal Word Warning
GHS Hazard statements H228
European Hazard Symbols Flammable Flammable (F)
MSDS Link Download
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
GHS Precautionary statements P210
Risk Statements 11
Storage Temperature 2-8°C
German water hazard class 1

DETAILS

Description (English)
Other Notes
No bulk orders
Packaging
100, 500 mg in glass bottle
2 g in glass bottle
Legal Information
US Patent No. 7,365,140 (and associated foreign equivalents) owned by UTI Limited Partnership and licensed to Materia; Inc. apply. Sale of this product conveys to the buyer a limited-use research license. For full details of this license please see sigma-aldrich.com/materialicense. For questions; please contact us at aldrich@sial.com or Materia at info@materia-inc.com.
Application

• Cationic 4-coordinate catalyst is considered “pre-activated” because no ligand dissociation is required for formation of the active catalytic species.
• Has reactivity profile similar to the Grubbs 1st Generation Catalyst but is active at much lower temperatures (below 0 °C).1
Description (简体中文)
Other Notes
不接受批量订单
包装
100, 500 mg in glass bottle
2 g in glass bottle
Legal Information
美国专利号 7,365,140(和相关国外等同专利)归 UTI Limited Partnership 所有,授权 Materia; Inc. 使用。销售该产品可向购买者转让限制使用研究许可。有关该许可的完整详细内容,请访问 sigma-aldrich.com/materialicense。如有疑问;请发送邮件至 aldrich@sial.com 与我们联系,或发送至 info@materia-inc.com 联系 Materia。
Application

• Cationic 4-coordinate catalyst is considered “pre-activated” because no ligand dissociation is required for formation of the active catalytic species.
• Has reactivity profile similar to the Grubbs 1st Generation Catalyst but is active at much lower temperatures (below 0 °C).1

REFERENCES