Dichloro(tricyclohexylphosphine)[(tricyclohexylphosphoranyl)methylidene]ruthenium(II) tetrafluoroborate

• Catalog No.: 707961
• CAS Number: 1020085-61-3
• M. F.: C37H67BCl2F4P2Ru
• M. W.: 832.6560148
• Purity: 95%

SYNONYMS

• Title: 二氯(三环己基膦)[(三环己基正膦基)亚甲基]四氟硼酸钌(II)
• IUPAC name: tetrafluoroboranuide; tricyclohexyl[(dichlororutheniumylidene)methyl]phosphanium; tricyclohexylphosphane
• IUPAC Traditional name: tricyclohexyl[(dichlororutheniumylidene)methyl]phosphanium tricyclohexylphosphine tetrafluoroborate
• Synonyms: Piers first generation metathesis catalyst; Dichloro(PCy3)[(tricyclohexylphosphoranyl)methylidene]Ru tetrafluoroborate; Piers 第一代复分解反应催化剂

DATABASE IDS

• MDL Number: MFCD15144782
• CAS Number: 1020085-61-3

PROPERTIES

• Empirical Formula (Hill Notation): C37H67BCl2F4P2Ru
• Purity: 95%
• Melting Point: 203 °C (dec.)
• GHS Signal Word: Warning
• GHS Hazard statements: H228
• European Hazard Symbols: Flammable (F)
• Personal Protective Equipment: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• GHS Precautionary statements: P210
• Risk Statements: 11
• Storage Temperature: 2-8°C
• German water hazard class: 1

DETAILS

Description (English)

Other Notes
No bulk orders
Packaging
100, 500 mg in glass bottle
2 g in glass bottle
Legal Information
US Patent No. 7,365,140 (and associated foreign equivalents) owned by UTI Limited Partnership and licensed to Materia; Inc. apply. Sale of this product conveys to the buyer a limited-use research license. For full details of this license please see sigma-aldrich.com/materialicense. For questions; please contact us at aldrich@sial.com or Materia at info@materia-inc.com.
Application

• Cationic 4-coordinate catalyst is considered “pre-activated” because no ligand dissociation is required for formation of the active catalytic species.
• Has reactivity profile similar to the Grubbs 1st Generation Catalyst but is active at much lower temperatures (below 0 °C).1

Description (简体中文)

Other Notes
不接受批量订单
包装
100, 500 mg in glass bottle
2 g in glass bottle
Legal Information
美国专利号 7,365,140（和相关国外等同专利）归 UTI Limited Partnership 所有，授权 Materia; Inc. 使用。销售该产品可向购买者转让限制使用研究许可。有关该许可的完整详细内容，请访问 sigma-aldrich.com/materialicense。如有疑问；请发送邮件至 aldrich@sial.com 与我们联系，或发送至 info@materia-inc.com 联系 Materia。
Application

• Cationic 4-coordinate catalyst is considered “pre-activated” because no ligand dissociation is required for formation of the active catalytic species.
• Has reactivity profile similar to the Grubbs 1st Generation Catalyst but is active at much lower temperatures (below 0 °C).1