Bis(3,5-dimethyl-4-methoxyphenyl)chlorophosphine

• Catalog No.: 695130
• CAS Number: 136802-85-2
• M. F.: C18H22ClO2P
• M. W.: 336.792841

SYNONYMS

• Title: 氯二(3,5-二甲基-4-甲氧苯基)膦
• IUPAC name: chlorobis(4-methoxy-3,5-dimethylphenyl)phosphane
• IUPAC Traditional name: chlorobis(4-methoxy-3,5-dimethylphenyl)phosphane

DATABASE IDS

• MDL Number: MFCD01630810
• CAS Number: 136802-85-2

PROPERTIES

• Empirical Formula (Hill Notation): C18H22ClO2P
• Density: 1.141 g/cm3 at 25 °C
• Flash Point: >110 °C
• Flash Point: >230 °F
• Refractive Index: n20/D 1.597
• GHS Signal Word: Danger
• GHS Hazard statements: H314
• European Hazard Symbols: Corrosive (C)
• Personal Protective Equipment: Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
• GHS Precautionary statements: P280-P305 + P351 + P338-P310
• RID/ADR: UN 1760 8/PG 3
• Risk Statements: 34
• Safety Statements: 26-36/37/39-43-45
• Hazard Class: 8
• UN Number: 1760
• Packing Group: 3
• German water hazard class: 3

DETAILS

Description (English)

Packaging
100, 500 mg in glass bottle
Application
Reactant for:
• Asymmetric organocatalytic electrophilic phosphination1
• Asymmetric hydroformulation using Taddol-based chiral phosphine-phosphite ligands2
• Synthesis of ferrocene-based chiral diphosphines3
• Alcoholysis of phosphane-boranes4
• Asymmetric hydrogenations of bifep-type biferrocenes5

Description (简体中文)

包装
100, 500 mg in glass bottle
Application
Reactant for:
• Asymmetric organocatalytic electrophilic phosphination1
• Asymmetric hydroformulation using Taddol-based chiral phosphine-phosphite ligands2
• Synthesis of ferrocene-based chiral diphosphines3
• Alcoholysis of phosphane-boranes4
• Asymmetric hydrogenations of bifep-type biferrocenes5