(S,S)-2-Allyl-1,3-bis-(4-bromobenzyl)-2-chlorooctahydro-2-1H-1,3,2-benzodiazasilole

• Catalog No.: 705098
• M. F.: C23H27Br2ClN2Si
• M. W.: 554.82038
• Purity: 95%

SYNONYMS

• Title: (S,S)-2-烯丙基-1,3-双(4-溴苯甲基)-2-氯八氢-2-1H-1,3,2-苯并二氮杂硅杂环戊二烯
• IUPAC name: (3aS,7aS)-1,3-bis[(4-bromophenyl)methyl]-2-chloro-2-(prop-2-en-1-yl)-octahydro-1H-1,3,2-benzodiazasilole
• IUPAC Traditional name: (3aS,7aS)-1,3-bis[(4-bromophenyl)methyl]-2-chloro-2-(prop-2-en-1-yl)-hexahydro-1,3,2-benzodiazasilole
• Synonyms: (S,S)-1,3-Bis-[(4-bromophenyl)methyl]-2-chlorooctahydro-2-(2-propenyl)-1H-1,3,2-benzodiazasilole; (S,S)-1,3-双[(4-溴苯基)甲基]-2-氯八氢-2-(2-丙烯基)-1H-1,3,2-苯并二氮杂硅杂环戊二烯

DATABASE IDS

• MDL Number: MFCD12546043

PROPERTIES

• Empirical Formula (Hill Notation): C23H27Br2ClN2Si
• Purity: 95%
• Melting Point: 94-99 °C
• Optical Rotation: [α]22/D +54°, c = 1 in chloroform
• GHS Signal Word: Warning
• GHS Hazard statements: H302
• European Hazard Symbols: Harmful (Xn)
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Faceshields, Gloves
• Risk Statements: 22
• Storage Temperature: 2-8°C
• German water hazard class: 2

DETAILS

Description (English)

Application
An operationally simple regioselective and enantioselective allylation of beta-diketones to provide tertiary carbinols1
Leighton’s Strained Silacycles: Powerful Enantioselective Allylation Reagents
Packaging
1, 5 g in glass bottle
Legal Information
U.S. Patent No. 7,534,905

Description (简体中文)

Application
An operationally simple regioselective and enantioselective allylation of beta-diketones to provide tertiary carbinols1
Leighton’s Strained Silacycles: Powerful Enantioselective Allylation Reagents
包装
1, 5 g in glass bottle
Legal Information
美国专利 No.7,534,905