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RuCl(p-cymene)[(R,R)-Ts-DPEN]_Molecular_structure_CAS_192139-92-7)
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RuCl(p-cymene)[(R,R)-Ts-DPEN]

Catalog No. 703907 Name Sigma Aldrich
CAS Number 192139-92-7 Website http://www.sigmaaldrich.com
M. F. C31H35ClN2O2RuS Telephone 1-800-521-8956
M. W. 636.2098 Fax
Purity Email
Storage Chembase ID: 142412

SYNONYMS

Title
RuCl(p-异丙基甲苯)[(R,R)-Ts-DPEN]
IUPAC name
1-methyl-4-(propan-2-yl)benzene; N-[(1R,2R)-2-amino-1,2-diphenylethyl]-N-(chlororuthenio)-4-methylbenzene-1-sulfonamide
IUPAC Traditional name
N-[(1R,2R)-2-amino-1,2-diphenylethyl]-N-(chlororuthenio)-4-methylbenzenesulfonamide; cymene
Synonyms
[N-[(1R,2R)-2-(氨基-κN)-1,2-二苯基乙基]-4-甲基苯磺酰胺合-κN]氯[(1,2,3,4,5,6-η)-1-甲基-4-(1-甲基乙基)苯]-钌
[N-[(1R,2R)-2-(Amino-κN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-κN]chloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]-ruthenium

DATABASE IDS

MDL Number MFCD10567385
CAS Number 192139-92-7

PROPERTIES

Empirical Formula (Hill Notation) C31H35ClN2O2RuS
Melting Point 215 °C
Optical Rotation [α]20/D -116°, c = 0.1 in chloroform
MSDS Link Download
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Storage Temperature 2-8°C
German water hazard class 3

DETAILS

Description (English)
Packaging
100, 500 mg in glass bottle
Legal Information
Sold in collaboration with Takasago for research purposes only. WO9720789
Application
Takasago Ligands and Complexes for Asymmetric Reactions
Phosphine cationic ruthenium catalysts used for enantioselective hydrogenation of:
• Quinolines
• N-Alkyl ketimines
• Antitumor and antiproliferative derivatives of natural products isolated from bacteria
• Hydroxy arylaldehydes via Rap-Stoermer-enantioselective transfer hydrogenationCatalyst with improved performance modified via microenvironment engineering of nanocages
Description (简体中文)
包装
100, 500 mg in glass bottle
Legal Information
与 Takasago 合作销售,仅用于研究目的。WO9720789
Application
Takasago Ligands and Complexes for Asymmetric Reactions
Phosphine cationic ruthenium catalysts used for enantioselective hydrogenation of:
• Quinolines
• N-Alkyl ketimines
• Antitumor and antiproliferative derivatives of natural products isolated from bacteria
• Hydroxy arylaldehydes via Rap-Stoermer-enantioselective transfer hydrogenationCatalyst with improved performance modified via microenvironment engineering of nanocages

REFERENCES