(S)-(+)-COP-Cl Catalyst

• Catalog No.: 646636
• CAS Number: 612065-01-7
• M. F.: C78H68Cl2Co2N2O2Pd2
• M. W.: 1466.99912

SYNONYMS

• Title: (S)-(+)-COP-Cl 催化剂
• IUPAC name: bis(λ^2-cobalt(2+) ion) bis(3-[(4R)-4-(propan-2-yl)-4,5-dihydro-1,3-oxazol-2-yl]cyclopenta-2,4-dien-1-ide) cyclodipalladachlorane-1,3-bis(ylium) bis(tetraphenylcyclobut-3-ene-1,2-diide)
• IUPAC Traditional name: bis(λ^2-cobalt(2+) ion) bis(3-[(4R)-4-isopropyl-4,5-dihydro-1,3-oxazol-2-yl]cyclopenta-2,4-dien-1-ide) cyclodipalladachlorane-1,3-bis(ylium) bis(tetraphenylcyclobut-3-ene-1,2-diide)

DATABASE IDS

• CAS Number: 612065-01-7
• PubChem SID: 24883474
• MDL Number: MFCD06798109

PROPERTIES

• Empirical Formula (Hill Notation): C78H66Cl2Co2N2O2Pd2
• Melting Point: 204-205 °C(lit.)
• Optical Rotation: [α]20/D +1201°, c = 0.1 in methylene chloride
• Personal Protective Equipment: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• German water hazard class: 3

DETAILS

Description (English)

Application
Catalyst employed in the rearrangement of allylic trichloracetimidates to allylic amines of high enantiopurity.3
Catalyst for:
• Enantioselective allylation of phenols with (E)-allylic alcohols to branched chiral allylic aryl ethers1
• Asymmetric aza-Claisen rearrangement and ring-closing metathesis2
Packaging
250 mg in glass bottle

Description (简体中文)

Application
用于钯催化重排三氯乙酰亚胺烯丙酯生成高对映纯烯丙胺的配体。3
Catalyst for:
• Enantioselective allylation of phenols with (E)-allylic alcohols to branched chiral allylic aryl ethers1
• Asymmetric aza-Claisen rearrangement and ring-closing metathesis2
包装
250 mg in glass bottle