Vinylboronic anhydride pyridine complex

• Catalog No.: 637998
• CAS Number: 442850-89-7
• M. F.: C11H14B3NO3
• M. W.: 240.66676
• Purity: 95%

SYNONYMS

• Title: 乙烯硼酐吡啶络合物
• IUPAC name: pyridine; triethenyl-1,3,5,2,4,6-trioxatriborinane
• IUPAC Traditional name: pyridine; triethenyl-1,3,5,2,4,6-trioxatriborinane
• Synonyms: 2,4,6-三乙烯基环硼氧烷吡啶络合物; Trivinylcyclotriboroxane pyridine complex; Trivinyl-boroxin pyridine complex; 2,4,6-Trivinylcyclotriboroxane pyridine complex

DATABASE IDS

• MDL Number: MFCD03839940
• PubChem SID: 24882902
• CAS Number: 442850-89-7

PROPERTIES

• Empirical Formula (Hill Notation): C6H9B3O3 · C5H5N
• Purity: 95%
• Flash Point: 80 °C
• Flash Point: 176 °F
• GHS Signal Word: Warning
• GHS Hazard statements: H319
• European Hazard Symbols: Irritant (Xi)
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves
• GHS Precautionary statements: P305 + P351 + P338
• Risk Statements: 36
• Safety Statements: 26
• Storage Temperature: -20°C
• German water hazard class: 3

DETAILS

Description (English)

Packaging
1, 5 g in glass bottle
Application
Reagent used for
• Suzuki-Miyaura cross-coupling1,2
• Stereoselective synthesis via Palladium-catalyzed carboamination3
• Alkyl-connected 2-amino-6-vinylpurine (AVP) crosslinking agent to cytosine base in RNA4
• Kaiser oxime resin-derived palladacycle as a recoverable polymeric precatalyst in Suzuki-Miyaura cross-coupling reactions in aqueous media5
• Kinetic resolution of phosphoryl and sulfonyl esters of binaphthol derivatives via Pd-catalyzed alcoholysis of their vinyl ethers6
• Stereoselective isomerization of N-allyl aziridines into Z-enamines by using rhodium hydride catalysis7
• Kinetic resolution of axially chiral biaryl derivatives via palladium/chiral diamine ligand-catalyzed alcoholysis8
• Transition metal-catalyzed alkenylation of aziridines, cycloaddition and thermal rearrangement reactions9
• Intramolecular Heck reaction strategy for synthesis of functionalized tetrahydroanthracenes10 Reagent used for Preparation of
• BACE-1 inhibitors and SAR of cyclic sulfone hydroxyethylamines11
• Distorted spiropentanes1
• Small molecule bradykinin B2 receptor antagonists in angioedema therapy12
• Enol Ethers13
• Styryl cyclobutanone

Description (简体中文)

包装
1, 5 g in glass bottle
Application
Reagent used for
• Suzuki-Miyaura cross-coupling1,2
• Stereoselective synthesis via Palladium-catalyzed carboamination3
• Alkyl-connected 2-amino-6-vinylpurine (AVP) crosslinking agent to cytosine base in RNA4
• Kaiser oxime resin-derived palladacycle as a recoverable polymeric precatalyst in Suzuki-Miyaura cross-coupling reactions in aqueous media5
• Kinetic resolution of phosphoryl and sulfonyl esters of binaphthol derivatives via Pd-catalyzed alcoholysis of their vinyl ethers6
• Stereoselective isomerization of N-allyl aziridines into Z-enamines by using rhodium hydride catalysis7
• Kinetic resolution of axially chiral biaryl derivatives via palladium/chiral diamine ligand-catalyzed alcoholysis8
• Transition metal-catalyzed alkenylation of aziridines, cycloaddition and thermal rearrangement reactions9
• Intramolecular Heck reaction strategy for synthesis of functionalized tetrahydroanthracenes10 Reagent used for Preparation of
• BACE-1 inhibitors and SAR of cyclic sulfone hydroxyethylamines11
• Distorted spiropentanes1
• Small molecule bradykinin B2 receptor antagonists in angioedema therapy12
• Enol Ethers13
• Styryl cyclobutanone