2-Dicyclohexylphosphino-2′-(N,N-dimethylamino)biphenyl

• Catalog No.: 638021
• CAS Number: 213697-53-1
• M. F.: C26H36NP
• M. W.: 393.544501
• Purity: 97%

SYNONYMS

• Title: 2-二环己膦基-2′-(N,N-二甲胺)联苯
• IUPAC name: 2-[2-(dicyclohexylphosphanyl)phenyl]-N,N-dimethylaniline
• IUPAC Traditional name: 2-[2-(dicyclohexylphosphanyl)phenyl]-N,N-dimethylaniline
• Synonyms: DavePhos

DATABASE IDS

• MDL Number: MFCD02183572
• PubChem SID: 24882905
• CAS Number: 213697-53-1

PROPERTIES

• Risk Statements: 36/37/38
• Safety Statements: 26
• German water hazard class: 3
• GHS Signal Word: Warning
• GHS Hazard statements: H315-H319-H335
• European Hazard Symbols: Irritant (Xi)
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves
• GHS Precautionary statements: P261-P305 + P351 + P338
• Empirical Formula (Hill Notation): C26H36NP
• Purity: 97%
• Ligand For: Arylations
• Ligand For: Buchwald-Hartwig Cross Coupling Reaction
• Ligand For: Hydroaminations
• Ligand For: Kumada Coupling
• Ligand For: Negishi Coupling
• Ligand For: Suzuki-Miyaura Coupling
• Melting Point: 121-124 °C(lit.)

DETAILS

Description (English)

Application
Ligand used in a Pd-catalyzed Suzuki aryl-aryl coupling leading to benzodioxepines.1
Useful ligand for Pd-catalyzed C-N bond formation; amination of aryl halides containing hydroxyl, amide, or enolizable ketones.
Packaging
1, 5, 25, 100 g in glass bottle
Legal Information
Usage subject to US Patents 6307087 and 6395916.

Description (简体中文)

Application
用于钯催化 C-N 键形成的有效配体；含羟基、酰胺或烯醇酮的芳基卤的胺化反应。
钯催化 Suzuki 芳基-芳基偶联反应的配体，生成苯并二噁庚英。1
包装
1, 5, 25, 100 g in glass bottle
Legal Information
用法以美国专利 6307087 和 6395916 为准。