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2-Dicyclohexylphosphino-2′-(N,N-dimethylamino)biphenyl_Molecular_structure_CAS_213697-53-1)
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2-Dicyclohexylphosphino-2′-(N,N-dimethylamino)biphenyl

Catalog No. 638021 Name Sigma Aldrich
CAS Number 213697-53-1 Website http://www.sigmaaldrich.com
M. F. C26H36NP Telephone 1-800-521-8956
M. W. 393.544501 Fax
Purity 97% Email
Storage Chembase ID: 10387

SYNONYMS

Title
2-二环己膦基-2′-(N,N-二甲胺)联苯
IUPAC name
2-[2-(dicyclohexylphosphanyl)phenyl]-N,N-dimethylaniline
IUPAC Traditional name
2-[2-(dicyclohexylphosphanyl)phenyl]-N,N-dimethylaniline
Synonyms
DavePhos

DATABASE IDS

MDL Number MFCD02183572
PubChem SID 24882905
CAS Number 213697-53-1

PROPERTIES

Risk Statements 36/37/38
Safety Statements 26
German water hazard class 3
GHS Pictograms GHS07
GHS Signal Word Warning
GHS Hazard statements H315-H319-H335
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
GHS Precautionary statements P261-P305 + P351 + P338
Empirical Formula (Hill Notation) C26H36NP
Purity 97%
Ligand For Arylations
Ligand For Buchwald-Hartwig Cross Coupling Reaction
Ligand For Hydroaminations
Ligand For Kumada Coupling
Ligand For Negishi Coupling
Ligand For Suzuki-Miyaura Coupling
Melting Point 121-124 °C(lit.)

DETAILS

Description (English)
Application
Ligand used in a Pd-catalyzed Suzuki aryl-aryl coupling leading to benzodioxepines.1
Useful ligand for Pd-catalyzed C-N bond formation; amination of aryl halides containing hydroxyl, amide, or enolizable ketones.
Packaging
1, 5, 25, 100 g in glass bottle
Legal Information
Usage subject to US Patents 6307087 and 6395916.
Description (简体中文)
Application
用于钯催化 C-N 键形成的有效配体;含羟基、酰胺或烯醇酮的芳基卤的胺化反应。
钯催化 Suzuki 芳基-芳基偶联反应的配体,生成苯并二噁庚英。1
包装
1, 5, 25, 100 g in glass bottle
Legal Information
用法以美国专利 6307087 和 6395916 为准。

REFERENCES