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1,2-Bis(dicyclohexylphosphino)ethane_Molecular_structure_CAS_23743-26-2)
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1,2-Bis(dicyclohexylphosphino)ethane

Catalog No. 479500 Name Sigma Aldrich
CAS Number 23743-26-2 Website http://www.sigmaaldrich.com
M. F. C26H48P2 Telephone 1-800-521-8956
M. W. 422.606842 Fax
Purity Email
Storage Chembase ID: 141957

SYNONYMS

Title
1,2-双(二环己基膦基)乙烷
IUPAC name
dicyclohexyl[2-(dicyclohexylphosphanyl)ethyl]phosphane
IUPAC Traditional name
dicyclohexyl[2-(dicyclohexylphosphanyl)ethyl]phosphane
Synonyms
Ethylenebis(dicyclohexylphosphine)
1,2-Ethanediylbis[dicyclohexyl]phosphine

DATABASE IDS

MDL Number MFCD00015521
CAS Number 23743-26-2
PubChem SID 24871622

PROPERTIES

Linear Formula (C6H11)2PCH2CH2PC6H11)2
Flash Point >110 °C
Flash Point >230 °F
Ligand For Decarboxylations
Ligand For Negishi Coupling
Ligand For Suzuki-Miyaura Coupling
Melting Point 92.5-96.5 °C(lit.)
MSDS Link Download
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
German water hazard class 3

DETAILS

Description (简体中文)
包装
1, 5 g in glass bottle
Application
Reactant involved in:
• Investigations of the role of ligand-based steric effects during the polymerization1
• Synthesis of molybdenum nitrosyl complexes for use as Imine hydrogenation catalysts2
• Irreversible thermal linkage isomerization of switchable C-N-bound isomers3
• Chelating for conversion of trans complexes to cis complexes4 Precursor for Iridium trisboryl complexes and the substituent effect on borylation reactions5Ligand for palladium(II) complex catalyzed hydrogenation reactions6
Description (English)
Packaging
1, 5 g in glass bottle
Application
Reactant involved in:
• Investigations of the role of ligand-based steric effects during the polymerization1
• Synthesis of molybdenum nitrosyl complexes for use as Imine hydrogenation catalysts2
• Irreversible thermal linkage isomerization of switchable C-N-bound isomers3
• Chelating for conversion of trans complexes to cis complexes4 Precursor for Iridium trisboryl complexes and the substituent effect on borylation reactions5Ligand for palladium(II) complex catalyzed hydrogenation reactions6

REFERENCES