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Deoxo-Fluor® solution_Molecular_structure_CAS_202289-38-1)
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Deoxo-Fluor® solution

Catalog No. 94327 Name Sigma Aldrich
CAS Number 202289-38-1 Website http://www.sigmaaldrich.com
M. F. C6H14F3NO2S Telephone 1-800-521-8956
M. W. 221.2410696 Fax
Purity Email
Storage Chembase ID: 9793

SYNONYMS

Title
Deoxo-Fluor® 溶液
IUPAC name
bis(2-methoxyethyl)(trifluoro-λ4-sulfanyl)amine
IUPAC Traditional name
bis(2-methoxyethyl)(trifluoro-λ4-sulfanyl)amine
Synonyms
双(2-甲氧基乙基)氨基三氟化硫 溶液
Bis(2-methoxyethyl)aminosulfur trifluoride solution

DATABASE IDS

PubChem SID 24889985
CAS Number 202289-38-1
MDL Number MFCD01321415

PROPERTIES

Concentration 50% in THF
Empirical Formula (Hill Notation) C6H14F3NO2S
Density 1.03-1.05 g/mL at 20 °C
Flash Point <10 °C
Flash Point <50 °F
GHS Pictograms GHS02
GHS Pictograms GHS05
GHS Pictograms GHS06
GHS Signal Word Danger
GHS Hazard statements H225-H261-H301 + H331-H314-H335
European Hazard Symbols Flammable Flammable (F)
European Hazard Symbols Toxic Toxic (T)
MSDS Link Download
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P210-P231 + P232-P261-P280-P301 + P310-P422
RID/ADR UN 3286 3/PG 2
Risk Statements 11-14-19-23/25-29-35-37
Safety Statements 16-26-36/37/39-45
Storage Temperature 2-8°C
Supplemental Hazard Statements Contact with water liberates toxic gas., May form explosive peroxides., Reacts violently with water.
Hazard Class 3
UN Number 3286
Packing Group 2
German water hazard class 3

DETAILS

Description (English)
Other Notes
Fluorinating agent with high thermal stability7,8,9
Packaging
10, 50 mL in PFA/FEP bottle
Application
Reactant for:
• Fluorination reactions1
• Preparation of fluorinated catechols via Umpolung based nucleophilic deoxyfluorination2
• Preparation of imidazole derivatives as CXCR3 antagonists3
• Ring expansion reactions4
• Synthesis of acyl azides from carboxylic acids5
• Aldehydes or ketones from carboxylic acids and Grignard reagents via in situ generation of Weinreb amides6
Legal Information
Deoxo-Fluor is a registered trademark of Air Products & Chemicals, Inc.
Description (简体中文)
Other Notes
具有高热稳定性的氟化剂7,8,9
包装
10, 50 mL in PFA/FEP btl
Application
Reactant for:
• Fluorination reactions1
• Preparation of fluorinated catechols via Umpolung based nucleophilic deoxyfluorination2
• Preparation of imidazole derivatives as CXCR3 antagonists3
• Ring expansion reactions4
• Synthesis of acyl azides from carboxylic acids5
• Aldehydes or ketones from carboxylic acids and Grignard reagents via in situ generation of Weinreb amides6
法律信息
Deoxo-Fluor 注册商标 Air Products & Chemicals, Inc.

REFERENCES