(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide

• Catalog No.: 700665
• CAS Number: 864943-22-6
• M. F.: C48H29O4P
• M. W.: 700.715221

SYNONYMS

• Title: (11bR)-2,6-二-9-菲基-4-羟基-二萘并[2,1-d:1′,2′-f][1,3,2]二噁磷杂庚英-4-氧化物
• IUPAC name: 13-hydroxy-10,16-bis(phenanthren-9-yl)-12,14-dioxa-13λ^5-phosphapentacyclo[13.8.0.0^2,^1^1.0^3,^8.0^1^8,^2^3]tricosa-1(23),2,4,6,8,10,15,17,19,21-decaen-13-one
• IUPAC Traditional name: 13-hydroxy-10,16-bis(phenanthren-9-yl)-12,14-dioxa-13λ^5-phosphapentacyclo[13.8.0.0^2,^1^1.0^3,^8.0^1^8,^2^3]tricosa-1(23),2,4,6,8,10,15,17,19,21-decaen-13-one
• Synonyms: (R)-3,3′-Bis(9-phenanthryl)-1,1′-binaphthalene-2,2′-diyl hydrogen phosphate

DATABASE IDS

• CAS Number: 864943-22-6
• MDL Number: MFCD12546016

PROPERTIES

• Empirical Formula (Hill Notation): C48H29O4P
• Melting Point: 390-400 °C
• Optical Rotation: [α]22/D -44.0°, c = 1 in DMSO
• Personal Protective Equipment: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• Storage Temperature: -20°C
• German water hazard class: 3

DETAILS

Description (English)

Packaging
100 mg in glass bottle
Application
Catalyst for:
• Asymmetric hydrogenation cascade1
• Enantioselective Friedel-Crafts reaction2
• Asymmetric hydrogenation of 2-substituted quinolines3
• Chiral Broensted acid catalyzed enantioselective a-aminoxylation of ene carbamates4
• Preparation of β-carbolines via diastereo- and enantioselective N-acyliminium cyclization cascades of tryptamines and keto acids/esters5
• Asymmetric transfer hydrogenation of substituted quinoxalines6

Description (简体中文)

包装
100 mg in glass bottle
Application
Catalyst for:
• Asymmetric hydrogenation cascade1
• Enantioselective Friedel-Crafts reaction2
• Asymmetric hydrogenation of 2-substituted quinolines3
• Chiral Broensted acid catalyzed enantioselective a-aminoxylation of ene carbamates4
• Preparation of β-carbolines via diastereo- and enantioselective N-acyliminium cyclization cascades of tryptamines and keto acids/esters5
• Asymmetric transfer hydrogenation of substituted quinoxalines6