Home > Compound List > Product Information
(1S,2S)-N,N′-Dihydroxy-N,N′-bis(diphenylacetyl)-1,2-cyclohexanediamine_Molecular_structure_CAS_1217464-22-6)
Click picture or here to close

(1S,2S)-N,N′-Dihydroxy-N,N′-bis(diphenylacetyl)-1,2-cyclohexanediamine

Catalog No. 700576 Name Sigma Aldrich
CAS Number 1217464-22-6 Website http://www.sigmaaldrich.com
M. F. C34H34N2O4 Telephone 1-800-521-8956
M. W. 534.64476 Fax
Purity 97% Email
Storage Chembase ID: 141689

SYNONYMS

Title
(1S,2S)-N,N′-二羟基-N,N′-双(二苯基乙酰基)-1,2-环己二胺
IUPAC name
N-hydroxy-N-[(1S,2S)-2-(N-hydroxy-2,2-diphenylacetamido)cyclohexyl]-2,2-diphenylacetamide
IUPAC Traditional name
N-hydroxy-N-[(1S,2S)-2-(N-hydroxy-2,2-diphenylacetamido)cyclohexyl]-2,2-diphenylacetamide
Synonyms
(S)-CBHA-DPA
(1S,2S)-N,N′-1,2-cyclohexanediylbis[N-hydroxy-α-phenyl-benzeneacetamide]
(1S,2S)-N,N′-1,2-环己二基双[N-羟基-α-苯基-苯乙酰胺]
(1S,2S)-N,N′-Dihydroxy-N,N′-bis(diphenylacetyl)-cyclohexane-1,2-diamine
(1S,2S)-N,N′-二羟基-N,N′-双(二苯基乙酰基)-环己烷-1,2-二胺

DATABASE IDS

MDL Number MFCD11044410
CAS Number 1217464-22-6

PROPERTIES

GHS Hazard statements H300
European Hazard Symbols Toxic Toxic (T)
MSDS Link Download
Personal Protective Equipment Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
GHS Precautionary statements P264-P301 + P310
RID/ADR UN 2811 6.1/PG 3
Risk Statements 25
Safety Statements 45
Hazard Class 6.1
UN Number 2811
Packing Group 3
German water hazard class 3
GHS Pictograms GHS06
GHS Signal Word Danger
Empirical Formula (Hill Notation) C34H34N2O4
Purity 97%
Melting Point 199-204 °C
Optical Rotation [α]22/D -79.0°, c = 1 in chloroform

DETAILS

Description (English)
Application
Ligand used with vanadium for asymmetric epoxidation of allylic alcohols1,2
Packaging
50 mg in glass bottle
Protocols & Applications
Asymmetric Oxidation with CHBA Ligands
Asymmetric Epoxidation of Allylic Alcohols
Asymmetric Epoxidation of Homoallylic Alcohols
Asymmetric Ketone Hydrogenation
Asymmetric Transfer Hydrogenation
Description (简体中文)
Application
与钒共同用于烯丙醇的不对称环氧化反应的配体1,2
包装
50 mg in glass bottle
Protocols & Applications
Asymmetric Oxidation with CHBA Ligands
Asymmetric Epoxidation of Allylic Alcohols
Asymmetric Epoxidation of Homoallylic Alcohols
Asymmetric Ketone Hydrogenation
Asymmetric Transfer Hydrogenation

REFERENCES