(1S,2S)-N,N′-Dihydroxy-N,N′-bis(diphenylacetyl)-1,2-cyclohexanediamine

• Catalog No.: 700576
• CAS Number: 1217464-22-6
• M. F.: C34H34N2O4
• M. W.: 534.64476
• Purity: 97%

SYNONYMS

• Title: (1S,2S)-N,N′-二羟基-N,N′-双(二苯基乙酰基)-1,2-环己二胺
• IUPAC name: N-hydroxy-N-[(1S,2S)-2-(N-hydroxy-2,2-diphenylacetamido)cyclohexyl]-2,2-diphenylacetamide
• IUPAC Traditional name: N-hydroxy-N-[(1S,2S)-2-(N-hydroxy-2,2-diphenylacetamido)cyclohexyl]-2,2-diphenylacetamide
• Synonyms: (S)-CBHA-DPA; (1S,2S)-N,N′-1,2-cyclohexanediylbis[N-hydroxy-α-phenyl-benzeneacetamide]; (1S,2S)-N,N′-1,2-环己二基双[N-羟基-α-苯基-苯乙酰胺]; (1S,2S)-N,N′-Dihydroxy-N,N′-bis(diphenylacetyl)-cyclohexane-1,2-diamine; (1S,2S)-N,N′-二羟基-N,N′-双(二苯基乙酰基)-环己烷-1,2-二胺

DATABASE IDS

• MDL Number: MFCD11044410
• CAS Number: 1217464-22-6

PROPERTIES

• GHS Hazard statements: H300
• European Hazard Symbols: Toxic (T)
• Personal Protective Equipment: Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
• GHS Precautionary statements: P264-P301 + P310
• RID/ADR: UN 2811 6.1/PG 3
• Risk Statements: 25
• Safety Statements: 45
• Hazard Class: 6.1
• UN Number: 2811
• Packing Group: 3
• German water hazard class: 3
• GHS Signal Word: Danger
• Empirical Formula (Hill Notation): C34H34N2O4
• Purity: 97%
• Melting Point: 199-204 °C
• Optical Rotation: [α]22/D -79.0°, c = 1 in chloroform

DETAILS

Description (English)

Application
Ligand used with vanadium for asymmetric epoxidation of allylic alcohols1,2
Packaging
50 mg in glass bottle
Protocols & Applications
Asymmetric Oxidation with CHBA Ligands
Asymmetric Epoxidation of Allylic Alcohols
Asymmetric Epoxidation of Homoallylic Alcohols
Asymmetric Ketone Hydrogenation
Asymmetric Transfer Hydrogenation

Description (简体中文)

Application
与钒共同用于烯丙醇的不对称环氧化反应的配体1,2
包装
50 mg in glass bottle
Protocols & Applications
Asymmetric Oxidation with CHBA Ligands
Asymmetric Epoxidation of Allylic Alcohols
Asymmetric Epoxidation of Homoallylic Alcohols
Asymmetric Ketone Hydrogenation
Asymmetric Transfer Hydrogenation