(S)-C3-TunePhos

• Catalog No.: 696064
• CAS Number: 486429-99-6
• M. F.: C39H32O2P2
• M. W.: 594.617702

SYNONYMS

• IUPAC name: [17-(diphenylphosphanyl)-8,12-dioxatricyclo[11.4.0.0^2,^7]heptadeca-1(13),2(7),3,5,14,16-hexaen-3-yl]diphenylphosphane
• IUPAC Traditional name: [17-(diphenylphosphanyl)-8,12-dioxatricyclo[11.4.0.0^2,^7]heptadeca-1(13),2(7),3,5,14,16-hexaen-3-yl]diphenylphosphane
• Synonyms: (S)-二(二苯基膦基)-7,8-二氢-6H-二苯并[f,h][1,5]二噁壬英; (S)-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin

DATABASE IDS

• MDL Number: MFCD06658115
• CAS Number: 486429-99-6

PROPERTIES

• German water hazard class: 3
• Personal Protective Equipment: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• Empirical Formula (Hill Notation): C39H32O2P2

DETAILS

Description (English)

Application
Provides comparable or superior enantioselectivities and catalytic abilities to BINAP in Ru-catalyzed asymmetric hydrogenations of β-keto esters5, cyclic β-(acylamino)acrylates6 and a-phthalimide ketones7.
Chiral Quest Phosphine Ligands for Asymmetric HydrogenationReactant for:
• Asymmetric hydrogenation of ketones with TunePhos/diamine/ruthenium complexes1
• Stereoselective preparation of arylalkyl esters via enantioselective hydrogenation of enol acetates2Precatalyst for:
• Enantioselective iridium-catalyzed carbonyl allylation from alcohol or aldehyde by transfer hydrogenative coupling of allyl acetate3Catalyst for:
• Enantioselective hydrogenation of a-keto esters to a-hydroxy esters using Ru-tunephos catalysts4
Packaging
100, 500 mg in glass bottle

Description (简体中文)

Application
在钌催化的 β-酮酯5、环 β-(酰胺基)丙烯酸酯6和 α-邻苯二甲酰亚胺酮7的不对称性氢化反应中可以提供与 BINAP 相当或更好的对映选择性以及催化能力。
Chiral Quest Phosphine Ligands for Asymmetric HydrogenationReactant for:
• Asymmetric hydrogenation of ketones with TunePhos/diamine/ruthenium complexes1
• Stereoselective preparation of arylalkyl esters via enantioselective hydrogenation of enol acetates2Precatalyst for:
• Enantioselective iridium-catalyzed carbonyl allylation from alcohol or aldehyde by transfer hydrogenative coupling of allyl acetate3Catalyst for:
• Enantioselective hydrogenation of a-keto esters to a-hydroxy esters using Ru-tunephos catalysts4
包装
100, 500 mg in glass bottle