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(R)-3,3′-Bis(9-anthracenyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate_Molecular_structure_CAS_361342-51-0)
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(R)-3,3′-Bis(9-anthracenyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate

Catalog No. 695718 Name Sigma Aldrich
CAS Number 361342-51-0 Website http://www.sigmaaldrich.com
M. F. C48H31O4P Telephone 1-800-521-8956
M. W. 702.731101 Fax
Purity 95% Email
Storage Chembase ID: 141625

SYNONYMS

Title
(R)-3,3′-双(9-蒽基)-1,1′-联萘-2,2′-二基磷酸氢酯
IUPAC name
10,16-bis(anthracen-9-yl)-13-hydroxy-12,14-dioxa-13λ5-phosphapentacyclo[13.8.0.02,11.03,8.018,23]tricosa-1(15),2,4,6,8,10,16,18(23),21-nonaen-13-one
IUPAC Traditional name
10,16-bis(anthracen-9-yl)-13-hydroxy-12,14-dioxa-13λ5-phosphapentacyclo[13.8.0.02,11.03,8.018,23]tricosa-1(15),2,4,6,8,10,16,18(23),21-nonaen-13-one
Synonyms
(11bR)-2,6-Di-9-anthracenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide
(11bR)-2,6-二-9-蒽基-4-羟基-二萘并[2,1-d:1′,2′-f][1,3,2]二噁磷杂庚英-4-氧化物

DATABASE IDS

CAS Number 361342-51-0

PROPERTIES

Empirical Formula (Hill Notation) C48H29O4P
Purity 95%
Melting Point 288-292 °C (D)
GHS Pictograms GHS07
GHS Signal Word Warning
GHS Hazard statements H315-H319-H335
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
GHS Precautionary statements P261-P305 + P351 + P338
Risk Statements 36/37/38
Safety Statements 26
Storage Temperature -20°C
German water hazard class 3

DETAILS

Description (English)
Application
Catalyst used in asymmetric direct alkylation of α-diazoester via C-H bond cleavage.1
Catalysts used in enantioselective condensation/amine addition reactions
Packaging
100, 500 mg in glass bottle
Protocols & Applications
Reductive Amination using BINOL-Derived Chiral Phosphoric Acids
Description (简体中文)
Application
用于 α-重氮酯经不对称直接烷基化使 C-H 键断裂的催化剂。1
用于不对称缩合/胺加成反应的催化剂
包装
100, 500 mg in glass bottle
Protocols & Applications
Reductive Amination using BINOL-Derived Chiral Phosphoric Acids

REFERENCES