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Chlorodicarbonyl(1-(isopropylamino)-2,3,4,5-tetraphenylcyclopentadienyl)ruthenium(II)_Molecular_structure_CAS_470688-18-7)
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Chlorodicarbonyl(1-(isopropylamino)-2,3,4,5-tetraphenylcyclopentadienyl)ruthenium(II)

Catalog No. 686190 Name Sigma Aldrich
CAS Number 470688-18-7 Website http://www.sigmaaldrich.com
M. F. C34H28ClNO2Ru Telephone 1-800-521-8956
M. W. 619.11462 Fax
Purity 96% Email
Storage Chembase ID: 141597

SYNONYMS

Title
氯二羰基(1-(异丙基氨基)-2,3,4,5-四苯基环戊二烯)钌(II)
IUPAC name
λ2-ruthenium(2+) ion 1,2,3,5-tetraphenyl-4-[(propan-2-yl)amino]cyclopenta-2,4-dien-1-ide bis(methanidylidyneoxidanium) chloride
IUPAC Traditional name
λ2-ruthenium(2+) ion 3-(isopropylamino)-1,2,4,5-tetraphenylcyclopenta-2,4-dien-1-ide bis(carbon monoxide) chloride
Synonyms
Dicarbonylchloro[(1,2,3,4,5-η)-1-[(1-methylethylamino]-2,3,4,5-tetraphenyl-2,4-cyclopentadien-1-yl]ruthenium
氯二羰基丙胺四苯基环戊二烯钌

DATABASE IDS

CAS Number 470688-18-7

PROPERTIES

Empirical Formula (Hill Notation) C34H28ClNO2Ru
Purity 96%
GHS Pictograms GHS07
GHS Signal Word Warning
GHS Hazard statements H315-H319-H335
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
GHS Precautionary statements P261-P305 + P351 + P338
Risk Statements 36/37/38
Safety Statements 26-36/37
German water hazard class 3

DETAILS

Description (English)
Application
Metal catalyst used in conjunction with enzymes for enantioselective transformations via dynamic kinetic resolution.6
Catalyst for asymmetric:
• Synthesis of achaetolide1
• Transfer hydrogenation and racemization2
• Total synthesis of stagonolide-C3Reactant for synthesis of air-stable racemization catalysts4Racemization catalyst for dynamic kinetic resolution of secondary alcohols5
Packaging
1 g in glass bottle
250 mg in glass bottle
Description (简体中文)
Application
用于与酶共同作用,通过动态动力学拆分来催化不对称转化的金属催化剂。6
Catalyst for asymmetric:
• Synthesis of achaetolide1
• Transfer hydrogenation and racemization2
• Total synthesis of stagonolide-C3Reactant for synthesis of air-stable racemization catalysts4Racemization catalyst for dynamic kinetic resolution of secondary alcohols5
包装
1 g in glass bottle
250 mg in glass bottle

REFERENCES