(4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1-oxa-3-aza-2-silacyclopentane

• Catalog No.: 706671
• CAS Number: 447440-43-9
• M. F.: C13H18ClNOSi
• M. W.: 267.82662

SYNONYMS

• Title: (4S,5S)-2-烯丙基-2-氯-3,4-二甲基-5-苯基-1-氧杂-3-氮杂-2-硅杂环戊烷
• IUPAC name: (4S,5S)-2-chloro-3,4-dimethyl-5-phenyl-2-(prop-2-en-1-yl)-1,3,2-oxazasilolidine
• IUPAC Traditional name: (4S,5S)-2-chloro-3,4-dimethyl-5-phenyl-2-(prop-2-en-1-yl)-1,3,2-oxazasilolidine
• Synonyms: (4S,5S)-2-Chloro-3,4-dimethyl-5-phenyl-2-(2-propenyl)-1-oxa-3-aza-2-silacyclopentane; (1S,2S)-pseudoephedrine allylchlorosilane; (1S,2S)-伪麻黄碱烯丙基氯硅烷; (4S,5S)-2-氯-3,4-二甲基-5-苯基-2-(2-丙烯基)-1-氧杂-3-氮杂-2-硅杂环戊烷; (4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1,3,2-oxazasilolidine; (4S,5S)-2-烯丙基-2-氯-3,4-二甲基-5-苯基-1,3,2-氧氮杂硅杂环戊烷

DATABASE IDS

• MDL Number: MFCD09953823
• CAS Number: 447440-43-9

PROPERTIES

• Empirical Formula (Hill Notation): C13H18ClNOSi
• Boiling Point: 120 °C/5 mmHg
• Density: 1.095 g/mL at 25 °C
• Flash Point: 38 °C
• Flash Point: 100.4 °F
• Optical Rotation: [α]20/D 72.5°, c = 0.6 in ethanol (200 proof)
• Refractive Index: n20/D 1.517
• GHS Signal Word: Danger
• GHS Hazard statements: H226-H261-H315-H319-H335
• European Hazard Symbols: Flammable (F)
• European Hazard Symbols: Irritant (Xi)
• Personal Protective Equipment: Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• GHS Precautionary statements: P231 + P232-P261-P305 + P351 + P338-P422
• Risk Statements: 10-15-36/37/38
• Safety Statements: 26
• German water hazard class: 3

DETAILS

Description (English)

Application
Reagent used in the enantioselective allylation of aldehydes3
Leighton’s Strained Silacycles: Powerful Enantioselective Allylation Reagents
• Practical, enantioselective allylation of acylhydrazones1
• Enantioselective allylation of ketimines: synthesis of tertiary carbinamines2
General description
This product is a mixture of diastereomers.
Packaging
1 g in glass bottle
Legal Information
U.S. Patent No. 7,534,905

Description (简体中文)

Application
用于醛的对映选择性烯丙基化反应的试剂。3
Leighton’s Strained Silacycles: Powerful Enantioselective Allylation Reagents
• Practical, enantioselective allylation of acylhydrazones1
• Enantioselective allylation of ketimines: synthesis of tertiary carbinamines2
General description
该产品为非对映异构体混合物。
包装
1 g in glass bottle
Legal Information
美国专利 No.7,534,905