(R)-(-)-3,3′-Bis(triphenylsilyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate

• Catalog No.: 674745
• CAS Number: 791616-55-2
• M. F.: C56H41O4PSi2
• M. W.: 865.067101
• Purity: 96%

SYNONYMS

• Title: (R)-(-)-3,3′-双(三苯甲硅烷基)-1,1′-联萘-2,2′-二酚磷酸酯
• IUPAC name: 13-hydroxy-10,16-bis(triphenylsilyl)-12,14-dioxa-13λ^5-phosphapentacyclo[13.8.0.0^2,^1^1.0^3,^8.0^1^8,^2^3]tricosa-1(23),2,4,6,8,10,15,17,19,21-decaen-13-one
• IUPAC Traditional name: 13-hydroxy-10,16-bis(triphenylsilyl)-12,14-dioxa-13λ^5-phosphapentacyclo[13.8.0.0^2,^1^1.0^3,^8.0^1^8,^2^3]tricosa-1(23),2,4,6,8,10,15,17,19,21-decaen-13-one
• Synonyms: (11bR)-4-羟基-2,6-双(三苯甲硅烷基)二萘并-[2,1-d:1′,2′f]-1,3,2-二恶磷环庚烷-4-氧化物; MacMillan TiPSY catalyst; (11bR)-4-Hydroxy-2,6-bis(triphenylsilyl)dinaphtho-[2,1-d:1′,2′f]-1,3,2-dioxaphosphepin 4-oxide; MacMillan TiPSY 催化剂; Carreira SALDIPAC Ligand

DATABASE IDS

• PubChem SID: 24885235
• MDL Number: MFCD09265079
• CAS Number: 791616-55-2

PROPERTIES

• Empirical Formula (Hill Notation): C56H41O4PSi2
• Purity: 96%
• Melting Point: 329-335 °C
• Optical Rotation: [α]22/D -197°, c = 1 in chloroform
• GHS Signal Word: Warning
• GHS Hazard statements: H315-H319-H335
• European Hazard Symbols: Irritant (Xi)
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves
• GHS Precautionary statements: P261-P305 + P351 + P338
• Risk Statements: 36/37/38
• Safety Statements: 26
• German water hazard class: 3

DETAILS

Description (English)

Application
Organocatalyst for the first enatioselective organocatalytic reductive amination reaction.1
Packaging
100 mg in glass bottle
Protocols & Applications
Reductive Amination using BINOL-Derived Chiral Phosphoric Acids

Description (简体中文)

Application
用于第一次不对称有机催化还原胺化反应的有机催化剂。1
包装
100 mg in glass bottle
Protocols & Applications
Reductive Amination using BINOL-Derived Chiral Phosphoric Acids