(R)-3,3′-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate

• Catalog No.: 674605
• CAS Number: 791616-62-1
• M. F.: C36H17F12O4P
• M. W.: 772.4723794
• Purity: 95%

SYNONYMS

• Title: (R)-3,3′-双[3,5-双(三氟甲基)苯基]-1,1′-联萘-2,2′-二基磷酸氢酯
• IUPAC name: 10,16-bis[3,5-bis(trifluoromethyl)phenyl]-13-hydroxy-12,14-dioxa-13λ^5-phosphapentacyclo[13.8.0.0^2,^1^1.0^3,^8.0^1^8,^2^3]tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaen-13-one
• IUPAC Traditional name: 10,16-bis[3,5-bis(trifluoromethyl)phenyl]-13-hydroxy-12,14-dioxa-13λ^5-phosphapentacyclo[13.8.0.0^2,^1^1.0^3,^8.0^1^8,^2^3]tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaen-13-one
• Synonyms: (11bR)-2,6-双[3,5-双(三氟甲基)苯基]-4-羟基二萘并[2,1-d:1′,2′-f]-1,3,2-二噁磷杂庚英 4-氧化物; (11bR)-2,6-Bis[3,5-bis(trifluoromethyl)phenyl]-4-hydroxydinaphtho[2,1-d:1′,2′-f]-1,3,2-dioxaphosphepin 4-oxide; (R)-3,3′-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1′-bi-2-naphthol cyclic monophosphate; (R)-3,3′-双[3,5-双(三氟甲基)苯基]-1,1′-二-2-萘酚环一磷酸酯

DATABASE IDS

• CAS Number: 791616-62-1
• MDL Number: MFCD08689863
• PubChem SID: 24885225

PROPERTIES

• Empirical Formula (Hill Notation): C36H17F12O4P
• Purity: 95%
• Melting Point: 162-175 °C
• Optical Rotation: [α]20/D -220°, c = 1 in chloroform (typical)
• GHS Signal Word: Warning
• GHS Hazard statements: H315-H319-H335
• European Hazard Symbols: Irritant (Xi)
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves
• GHS Precautionary statements: P261-P305 + P351 + P338
• Risk Statements: 36/37/38
• Safety Statements: 26
• German water hazard class: 3

DETAILS

Description (English)

Application
As a chiral Bronsted acid, BINOL- derived cyclic phosphoric acid (such as Akiyama chiral Bronsted acid) was also shown to be an efficient catalyst for the hydrophosphonylation of aldimines at room temperature.1
Packaging
100 mg in glass bottle
Protocols & Applications
Reductive Amination using BINOL-Derived Chiral Phosphoric Acids

Description (简体中文)

Application
作为手性布朗斯特酸，BINOL- 衍生的环磷酸（例如 Akiyama 手性布朗斯特酸）还被证明为室温下亚胺醛磷酰化的高效催化剂。1
包装
100 mg in glass bottle
Protocols & Applications
Reductive Amination using BINOL-Derived Chiral Phosphoric Acids