(S)-2-[[(1R,2R)-2-[[[3,5-Bis(tert-butyl)-2-hydroxyphenyl]methylene]amino]cyclohexyl]thioureido]-N-benzyl-N,3,3-trimethylbutanamide

• Catalog No.: 693472
• CAS Number: 479423-24-0
• M. F.: C36H54N4O2S
• M. W.: 606.90456

SYNONYMS

• Title: (S)-2-[[(1R,2R)-2-[[[3,5-双(叔丁基)-2-羟苯基]亚甲基]氨基]环己基]硫脲基]-N-苄基-N,3,3-三甲基丁酰胺
• IUPAC name: (2S)-N-benzyl-2-({[(1R,2R)-2-{[(3,5-di-tert-butyl-2-hydroxyphenyl)methylidene]amino}cyclohexyl]carbamothioyl}amino)-N,3,3-trimethylbutanamide
• IUPAC Traditional name: (2S)-N-benzyl-2-({[(1R,2R)-2-{[(3,5-di-tert-butyl-2-hydroxyphenyl)methylidene]amino}cyclohexyl]carbamothioyl}amino)-N,3,3-trimethylbutanamide
• Synonyms: (2S)-2-[[[[(1R,2R)-2-[[[3,5-Bis(tert-butyl)-2-hydroxyphenyl]methylene]amino]cyclohexyl]amino]thioxomethyl]amino]-N-benzyl-N,3,3-trimethylbutanamide; (2S)-2-[[[[(1R,2R)-2-[[[3,5-双(1,1-二甲基乙基)-2-羟苯基]亚甲基]氨基]环己基]氨基]硫代甲基]氨基]-N,3,3-三甲基-N-(苯基甲基)丁酰胺; (2S)-2-[[[[(1R,2R)-2-[[[3,5-双(叔丁基)-2-羟苯基]亚甲基]氨基]环己基]氨基]硫代甲基]氨基]-N-苄基-N,3,3-三甲基丁酰胺; (2S)-2-[[[[(1R,2R)-2-[[[3,5-Bis(1,1-dimethylethyl)-2-hydroxyphenyl]methylene]amino]cyclohexyl]amino]thioxomethyl]amino]-N,3,3-trimethyl-N-(phenylmethyl)butanamide

DATABASE IDS

• CAS Number: 479423-24-0
• MDL Number: MFCD10567036

PROPERTIES

• Empirical Formula (Hill Notation): C36H54N4O2S
• Grade: technical grade
• Melting Point: 153-163 °C
• Optical Rotation: [α]22/D -99°, c = 1 in chloroform
• GHS Signal Word: Warning
• GHS Hazard statements: H315-H319-H335
• European Hazard Symbols: Irritant (Xi)
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves
• GHS Precautionary statements: P261-P305 + P351 + P338
• Risk Statements: 36/37/38
• Safety Statements: 26-36/37
• German water hazard class: 3

DETAILS

Description (English)

Application
Catalyst for the Mannich reaction5
Catalyst involved in:
• Enantioselective Pictet-Spengler-type cyclizations of hydroxylactams1
• Aza-Baylid-Hillman reactions2
• Hydrophosphonylation of imines3
• Studies of the effect of structure of molecule on asymmetric Strecker and Mannich reactions4
Packaging
100, 500 mg in glass bottle
Protocols & Applications
Asymmetric Strecker Reactions using Jacobsen Thioureas

Description (简体中文)

Application
Mannich 反应催化剂5
Catalyst involved in:
• Enantioselective Pictet-Spengler-type cyclizations of hydroxylactams1
• Aza-Baylid-Hillman reactions2
• Hydrophosphonylation of imines3
• Studies of the effect of structure of molecule on asymmetric Strecker and Mannich reactions4
包装
100, 500 mg in glass bottle
Protocols & Applications
Asymmetric Strecker Reactions using Jacobsen Thioureas