(S)-(-)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine)

• Catalog No.: 29511
• CAS Number: 133545-17-2
• M. F.: C38H32O2P2
• M. W.: 582.607002
• Purity: ≥97%

SYNONYMS

• Title: (S)-(-)-(6,6′-二甲氧联苯-2,2′-二基)双(二苯基膦)
• IUPAC name: {2-[2-(diphenylphosphanyl)-6-methoxyphenyl]-3-methoxyphenyl}diphenylphosphane
• IUPAC Traditional name: {2-[2-(diphenylphosphanyl)-6-methoxyphenyl]-3-methoxyphenyl}diphenylphosphane
• Synonyms: (S)-(-)-2,2′-Bis(diphenylphosphino)-6,6′-dimethoxy-1,1′-biphenyl; SL-A101-2; (S)-(-)-MeO-BIPHEP; (S)-(-)-2,2′-双(二苯基膦)-6,6′-二甲氧-1,1′-联苯

DATABASE IDS

• CAS Number: 133545-17-2
• Beilstein Number: 4790083
• PubChem SID: 24857759
• MDL Number: MFCD03095430

PROPERTIES

• Empirical Formula (Hill Notation): C38H32O2P2
• Optical Purity: ee: ≥99%
• Purity: ≥97%
• Personal Protective Equipment: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• German water hazard class: 3

DETAILS

Description (English)

General description
sold in collaboration with Solvias AG
Packaging
1, 5 g in glass bottle
100, 500 mg in glass bottle
Application
Atropisomeric MeOBIPHEP ligands
• C-C coupling reactions1
• Ligand for palladium-catalyzed intramolecular allylic alkylation of unsaturated amides2
• Enantioselective hydrogenation of a-amino-β-keto ester hydrochlorides catalyzed by an iridium complex3
• Asymmetric hydrogenation of aromatic ketones4

Description (简体中文)

General description
与 Solvias AG 联合销售
包装
1, 5 g in glass bottle
100, 500 mg in glass bottle
Application
Atropisomeric MeOBIPHEP ligands
• C-C coupling reactions1
• Ligand for palladium-catalyzed intramolecular allylic alkylation of unsaturated amides2
• Enantioselective hydrogenation of a-amino-β-keto ester hydrochlorides catalyzed by an iridium complex3
• Asymmetric hydrogenation of aromatic ketones4