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(+)-1-Benzyl-[(3R,4R)-bis(diphenylphosphino)]pyrrolidine(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate_Molecular_structure_CAS_99143-48-3)
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(+)-1-Benzyl-[(3R,4R)-bis(diphenylphosphino)]pyrrolidine(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

Catalog No. 672777 Name Sigma Aldrich
CAS Number 99143-48-3 Website http://www.sigmaaldrich.com
M. F. C43H45BF4NP2Rh Telephone 1-800-521-8956
M. W. 827.4817348 Fax
Purity ≥98% (31P-NMR) Email
Storage Chembase ID: 141346

SYNONYMS

Title
(+)-1-苄基-[(3R,4R)-双(二苯基膦)]吡咯烷(1,5-环辛二烯)四氟硼酸铑(I)
IUPAC name
λ1-rhodium(1+) ion (1Z,5Z)-cycloocta-1,5-diene (3R,4R)-1-benzyl-3,4-bis(diphenylphosphanyl)pyrrolidine tetrafluoroboranuide
IUPAC Traditional name
λ1-rhodium(1+) ion (3R,4R)-1-benzyl-3,4-bis(diphenylphosphanyl)pyrrolidine 1,5-cyclooctadiene tetrafluoroborate
Synonyms
catASium® D(R)Rh
(3R-trans)-3,4-Bis(diphenylphosphino)-1-(phenylmethyl)pyrrolidine rhodium complex
(3R-反式)-3,4-双(二苯基膦)-1-(苯基甲基)吡咯烷铑络合物

DATABASE IDS

CAS Number 99143-48-3
MDL Number MFCD05861620

PROPERTIES

Empirical Formula (Hill Notation) C43H45BF4NP2Rh
Purity ≥98% (31P-NMR)
Purity 98%
GHS Pictograms GHS07
GHS Signal Word Warning
GHS Hazard statements H315-H319-H335
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
GHS Precautionary statements P261-P305 + P351 + P338
Risk Statements 36/37/38
Safety Statements 26
German water hazard class 3

DETAILS

Description (English)
General description
sold in collaboration with Solvias AG
Packaging
500 mg in glass bottle
Application
Essential Elements for Asymmetric Hydrogenations
Legal Information
catASium is a registered trademark of Evonik Degussa GmbH
Description (简体中文)
General description
与 Solvias AG 联合销售
包装
500 mg in glass bottle
Application
Essential Elements for Asymmetric Hydrogenations
法律信息
catASium 注册商标 Evonik Degussa GmbH

REFERENCES