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1,2-Bis[(2S,5S)-2,5-diisopropylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate_Molecular_structure_CAS_1000393-36-1)
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1,2-Bis[(2S,5S)-2,5-diisopropylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

Catalog No. 698334 Name Sigma Aldrich
CAS Number 1000393-36-1 Website http://www.sigmaaldrich.com
M. F. C34H56BF4P2Rh Telephone 1-800-521-8956
M. W. 716.4660748 Fax
Purity Email
Storage Chembase ID: 141319

SYNONYMS

Title
1,2-双[(2S,5S)-2,5-二异丙基膦烷基]苯(1,5-环辛二烯)四氟硼酸铑(I)
IUPAC name
λ1-rhodium(1+) ion (2S,5S)-1-{2-[(2S,5S)-2,5-bis(propan-2-yl)phospholan-1-yl]phenyl}-2,5-bis(propan-2-yl)phospholane cycloocta-1,5-diene tetrafluoroboranuide
IUPAC Traditional name
λ1-rhodium(1+) ion (2S,5S)-1-{2-[(2S,5S)-2,5-diisopropylphospholan-1-yl]phenyl}-2,5-diisopropylphospholane 1,5-cyclooctadiene tetrafluoroborate

DATABASE IDS

CAS Number 1000393-36-1
MDL Number MFCD07369040

PROPERTIES

Empirical Formula (Hill Notation) C34H56BF4P2Rh
Optical Rotation [α]20/D 82, c = 0.8 in chloroform
MSDS Link Download
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
German water hazard class 3

DETAILS

Description (English)
Packaging
50, 250 mg in glass bottle
Legal Information
Sold in collaboration with Kanata Chemical Technologies Inc. for research purposes only. These compounds were made and sold under license from E.I. du Pont de Nemours and Company, which license does not include the right to use the compounds in producing products for sale in the pharmaceutical field.
Application
DuPhos and BPE Ligands: Highly Efficient Privileged Ligands
• Catalyst for asymmetric hydrogenation reactions1,2
Description (简体中文)
包装
50, 250 mg in glass bottle
Legal Information
与 Kanata Chemical Technologies Inc. 联合销售,仅供研究使用。这些化合物由 E.I. du Pont de Nemours and Company 授权制造和销售,此许可不包括利用这些化合物制备在制药领域销售的产品的权利。
Application
DuPhos and BPE Ligands: Highly Efficient Privileged Ligands
• Catalyst for asymmetric hydrogenation reactions1,2

REFERENCES