13,6-N-Sulfinylacetamidopentacene

• Catalog No.: 666025
• CAS Number: 454675-76-4
• M. F.: C24H17NO2S
• M. W.: 383.46228
• Purity: 97%

SYNONYMS

• Title: 13,6-N-亚磺酰基乙酰氨基并五苯
• IUPAC name: (1s,12s)-24-acetyl-23λ^4-thia-24-azahexacyclo[10.10.2.0^2,^1^1.0^4,^9.0^1^3,^2^2.0^1^5,^2^0]tetracosa-2(11),3,5,7,9,13(22),14,16,18,20-decaen-23-one
• IUPAC Traditional name: (1s,12s)-24-acetyl-23λ^4-thia-24-azahexacyclo[10.10.2.0^2,^1^1.0^4,^9.0^1^3,^2^2.0^1^5,^2^0]tetracosa-2(11),3,5,7,9,13(22),14,16,18,20-decaen-23-one
• Synonyms: NSFAAP; 16-Acetyl-6,13-dihydro-15-oxide -13,6-(epithioimino)pentacene; soluble pentacene precursor; 16-乙酰基-6,13-二氢-15-氧化物-13,6-(环硫亚氨基)并五苯; 可溶性并五苯前体

DATABASE IDS

• CAS Number: 454675-76-4
• MDL Number: MFCD08457646
• PubChem SID: 24884196

PROPERTIES

• Empirical Formula (Hill Notation): C24H17NO2S
• Purity: 97%
• Fluorescence: λex 251 nm; λem 498 nm in chloroform
• Melting Point: 169-190 °C
• Solubility: THF: soluble
• Solubility: dioxane: soluble
• Solubility: methylene chloride: soluble
• European Hazard Symbols: Nature polluting (N)
• Personal Protective Equipment: Eyeshields, Gloves
• RID/ADR: UN 3077 9/PG 3
• Risk Statements: 51/53
• Safety Statements: 61
• Storage Temperature: -20°C
• Hazard Class: 9
• UN Number: 3077
• Packing Group: 3
• German water hazard class: 3

DETAILS

Description (English)

Application
Pentacene precursor highly soluble (>50mg/ml) in apolar solvents (halogenated solvents, THF). Converted to pentacene in thin (e.g. spin-cast) films by heating under N2 atmosphere for 5-15 minutes at 120-200°C. Organic thin-film transistors fabricated by solution processing of this precursor afforded highest mobilities - up to 0.8cm2V-1s-1 - reported for a solution-processed organic semiconductor.1
This material is highly soluble in CHCl3, MeOH, THF, PGMEA, and other solvents that are commonly used in microelectronics processing.
Packaging
100, 200, 500 mg in glass bottle
Preparation Note
Dried thin films convert to pentacene at 150-200 °C
Protocols & Applications
Fabrication of Organic Field Effect Transistor Device Using a Soluble Pentacene Precursor

Description (简体中文)

Application
并五苯前体，易溶于非极性溶剂（卤化溶剂，THF）(>50mg/ml)。当在 N2 气氛中 120-200°C 下加热 5-15 分钟时，可转化为并五苯薄膜（如旋转涂布）。采用溶液法处理该前体可制备有机薄膜晶体管，其具有最高迁移率达到 0.8cm2V-1s-1（目前所记录的溶液制程的有机半导体）。1
这种材料易溶于 CHCl3、MeOH、THF、PGMEA 以及微电子工艺中常用的其他溶剂。
包装
100, 200, 500 mg in glass bottle
Preparation Note
干燥薄膜在 150-200°C 时可转化为并五苯
Protocols & Applications
Fabrication of Organic Field Effect Transistor Device Using a Soluble Pentacene Precursor