(S)-VAPOL hydrogenphosphate

• Catalog No.: 688320
• CAS Number: 871130-17-5
• M. F.: C40H25O4P
• M. W.: 600.597861

SYNONYMS

• Title: (S)-VAPOL 磷酸氢酯
• IUPAC name: 17-hydroxy-3,31-diphenyl-16,18-dioxa-17λ^5-phosphaheptacyclo[17.12.0.0^2,^1^5.0^5,^1^4.0^8,^1^3.0^2^0,^2^9.0^2^1,^2^6]hentriaconta-1(31),2,4,6,8,10,12,14,19,21,23,25,27,29-tetradecaen-17-one
• IUPAC Traditional name: 17-hydroxy-3,31-diphenyl-16,18-dioxa-17λ^5-phosphaheptacyclo[17.12.0.0^2,^1^5.0^5,^1^4.0^8,^1^3.0^2^0,^2^9.0^2^1,^2^6]hentriaconta-1(31),2,4,6,8,10,12,14,19,21,23,25,27,29-tetradecaen-17-one
• Synonyms: (S)-18-羟基-8,9-二苯基-联菲并[4,3-d:3′,4′-f][1,3,2]二噁磷杂庚英-18-氧化物; (S)-18-Hydroxy-8,9-diphenyl-diphenanthro[4,3-d:3′,4′-f][1,3,2]dioxaphosphepin-18-oxide; (S)-2,2′-Diphenyl-3,3′-biphenanthryl-4,4′-diyl phosphate; (S)-VAPOL phosphoric acid; (S)-VAPOL 磷酸; (S)-2,2′-二苯基-3,3′-联菲-4,4′-二基磷酸酯

DATABASE IDS

• CAS Number: 871130-17-5
• MDL Number: MFCD09265084

PROPERTIES

• Empirical Formula (Hill Notation): C40H25O4P
• Melting Point: >400 °C
• Optical Rotation: [α]22/D +412°, c = 1 in chloroform
• Personal Protective Equipment: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• German water hazard class: 3

DETAILS

Description (English)

Packaging
100, 500 mg in glass bottle
Application
Catalyst for:
• Benzoyloxylation of (aryl)oxindoles with benzoyl peroxide1
• Enantioselective synthesis of homoaldols and cyclic acetals via kinetic resoln of homoaldols2
• Desymmetrization of mono- and bicyclic N-acyl meso-aziridines by ring opening3,4
• Highly enantioselective addition of imides to imines to give aminals5
• Friedel-Crafts reaction of pyrroles with benzylidenebenzamides6

Description (简体中文)

包装
100, 500 mg in glass bottle
Application
Catalyst for:
• Benzoyloxylation of (aryl)oxindoles with benzoyl peroxide1
• Enantioselective synthesis of homoaldols and cyclic acetals via kinetic resoln of homoaldols2
• Desymmetrization of mono- and bicyclic N-acyl meso-aziridines by ring opening3,4
• Highly enantioselective addition of imides to imines to give aminals5
• Friedel-Crafts reaction of pyrroles with benzylidenebenzamides6