Chlorodicarbonyl(1,2,3,4,5-pentaphenylcyclopentadienyl)ruthenium(II)

• Catalog No.: 686441
• CAS Number: 677736-23-1
• M. F.: C37H25ClO2Ru
• M. W.: 638.1162

SYNONYMS

• Title: 氯二羰基(1,2,3,4,5-五苯基环戊二烯基)钌(II)
• IUPAC name: chlororutheniumylium; bis(methanidylidyneoxidanium); pentaphenylcyclopenta-2,4-dien-1-ide
• IUPAC Traditional name: bis(carbon monoxide); chlororutheniumylium; pentaphenylcyclopenta-2,4-dien-1-ide
• Synonyms: 二羰基氯[(1,2,3,4,5,-η)-1,2,3,4,5-五苯基环-2,4-戊二烯-1-基)]钌; Dicarbonylchloro[(1,2,3,4,5,-η)-1,2,3,4,5-pentaphenylcyclo-2,4-pentadien-1-yl)]ruthenium

DATABASE IDS

• CAS Number: 677736-23-1
• MDL Number: MFCD09265041

PROPERTIES

• Empirical Formula (Hill Notation): C37H25ClO2Ru
• Melting Point: 152-167 °C
• GHS Signal Word: Warning
• GHS Hazard statements: H315-H319-H335
• European Hazard Symbols: Irritant (Xi)
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves
• GHS Precautionary statements: P261-P305 + P351 + P338
• Risk Statements: 36/37/38
• Safety Statements: 26
• German water hazard class: 3

DETAILS

Description (English)

Packaging
1 g in glass bottle
250 mg in glass bottle
Legal Information
Product of Kanata Chemical Technologies, Inc.
Application
Reactant for:
• Synthesis of cyclopentadienyl ruthenium dicarbonyl catalyst1
• Ligand exchange2
• Formation of cyclopentadienyl ruthenium alkoxycarbonylcomplexes with coordinated C:C bonds3Catalyst for:
• (S)-Selective dynamic kinetic resolution of secondary alcohols4
• Stereoselective synthesis of neonicorinoide pesticide derivatives5
• Divergent asymmetric synthesis of 3,5-disubstituted piperidines6
Citation
Metal catalyst used in conjunction with enzymes for enantioselective transformations via dynamic kinetic resolution7

Description (简体中文)

包装
1 g in glass bottle
250 mg in glass bottle
Legal Information
Kanata Chemical Technologies, Inc. 产品
Application
Reactant for:
• Synthesis of cyclopentadienyl ruthenium dicarbonyl catalyst1
• Ligand exchange2
• Formation of cyclopentadienyl ruthenium alkoxycarbonylcomplexes with coordinated C:C bonds3Catalyst for:
• (S)-Selective dynamic kinetic resolution of secondary alcohols4
• Stereoselective synthesis of neonicorinoide pesticide derivatives5
• Divergent asymmetric synthesis of 3,5-disubstituted piperidines6
Citation
用于与酶共同作用，通过动态动力学拆分来催化不对称转化的金属催化剂7