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(R,R,R)-1-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a′]dinaphthalen-4-yl)-2,5-diphenylpyrrolidine_Molecular_structure_CAS_444667-33-8)
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(R,R,R)-1-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a′]dinaphthalen-4-yl)-2,5-diphenylpyrrolidine

Catalog No. 692697 Name Sigma Aldrich
CAS Number 444667-33-8 Website http://www.sigmaaldrich.com
M. F. C36H54NO2P Telephone 1-800-521-8956
M. W. 563.793221 Fax
Purity 90% Email
Storage Chembase ID: 141145

SYNONYMS

Title
(R,R,R)-1-(3,5-二氧杂-4-磷杂环庚二烯并[2,1-a:3,4-a′]二萘-4-基)-2,5-二苯基吡咯烷
IUPAC name
(2R,5R)-2-cyclohexyl-1-{12,14-dioxa-13-phosphapentacyclo[13.8.0.02,11.03,8.018,23]tricosan-13-yl}-5-phenylpyrrolidine
IUPAC Traditional name
(2R,5R)-2-cyclohexyl-1-{12,14-dioxa-13-phosphapentacyclo[13.8.0.02,11.03,8.018,23]tricosan-13-yl}-5-phenylpyrrolidine
Synonyms
1-(11bR)-Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl-(2R,5R)-2,5-diphenylpyrrolidine

DATABASE IDS

MDL Number MFCD16621390
CAS Number 444667-33-8

PROPERTIES

Empirical Formula (Hill Notation) C36H28NO2P
Purity 90%
Melting Point 191-196 °C
Optical Rotation [α]22/D -237°, c = 0.5 in chloroform
MSDS Link Download
Storage Temperature -20°C
German water hazard class 3

DETAILS

Description (English)
Application
Used in asymmetric hydrogenation.
DSM MonoPhos Family of Highly Efficient Privileged Ligands
Packaging
100, 500 mg in glass bottle
Legal Information
Sold under license from DSM for research purposes only.
Description (简体中文)
Application
用于不对称氢化反应。
DSM MonoPhos Family of Highly Efficient Privileged Ligands
包装
100, 500 mg in glass bottle
Legal Information
经 DSM 授权销售,仅供研究使用。

REFERENCES